Bimetal Cu and Fe modified g-C3N4sheets grown on carbon skeleton for efficient and selective photocatalytic reduction of CO2to CO

Bian，Songyuan1; Li，Xueyan2; Zhang，Long1; Wang，Libin1; Wang，Jingzhen1; Xu，Qing1; Zang，Linlin3; Zhang，Yanhong1; Sun，Liguo1

2023-04-01

10.1016/j.jece.2023.109319

Journal of Environmental Chemical Engineering   影响因子和分区

2213-2929

2213-3437

Excessive consumption of fossil fuels leads to resource shortages and the greenhouse effect. In order to solve these problems, the conversion of CO2 to fuel using photocatalytic technology has attracted extensive attention. In this work, Cu and Fe bimetallic modified g-C3N4 sheets grown on carbonized pomelo peels (Cu/Fe-CNC) for photocatalytic reduction CO2 to CO were synthesized via chemical vapor co-deposition (CVD) method. The modification by Cu and Fe bimetallic has enhanced the transfer and separation efficiency of charge carrier and increased surface reaction sites, thereby significantly enhancing the CO yield. Compared with the bulk g-C3N4, the reduction yield of CO2 to CO is increased by 3 times and compared with C3N4 grown on carbonized pomelo peel (CNC), it increased by 2 times. And Cu/Fe-CNC can achieve 100 % reduction of CO2 to CO in the photocatalytic system. Furthermore, the Cu/Fe-CNC has excellent stability in 5 cycle experiments. This work, from a new perspective, assists in developing high active g-C3N4-based photocatalysts to achieve the efficient and selective CO2 to CO reduction.

Bimetal Cu and Fe C3N4sheets Chemical vapor co-deposition Photocatalysts Selective reduction

SCI ; EI

英语

其他

National Natural Science Foundation of China[51973051] ; Heilongjiang Natural Science Foundation Project[LH2020E107]

Engineering

Engineering, Environmental ; Engineering, Chemical

WOS:000998405600001

ELSEVIER SCI LTD

20230513474811

Bimetals ; Carbon ; Chemical vapor deposition ; Copper ; Fossil fuels ; Greenhouse effect ; Iron ; Surface reactions

Atmospheric Properties:443.1 ; Air Pollution:451 ; Metallurgy and Metallography:531 ; Copper:544.1 ; Iron:545.1 ; Chemical Reactions:802.2 ; Chemical Products Generally:804 ; Inorganic Compounds:804.2

2-s2.0-85147092575

Scopus

1.School of Chemical Engineering and Materials,Heilongjiang University,Harbin,150080,China
2.School of Environmental Sciences and Engineering,Suzhou University of Science and Technology,Suzhou,215009,China
3.School of Environmental Science and Engineering,Southern University of Science and Technology,Shenzhen,518055,China

Bian，Songyuan,Li，Xueyan,Zhang，Long,et al. Bimetal Cu and Fe modified g-C3N4sheets grown on carbon skeleton for efficient and selective photocatalytic reduction of CO2to CO[J]. Journal of Environmental Chemical Engineering,2023,11(2).

Bian，Songyuan.,Li，Xueyan.,Zhang，Long.,Wang，Libin.,Wang，Jingzhen.,...&Sun，Liguo.(2023).Bimetal Cu and Fe modified g-C3N4sheets grown on carbon skeleton for efficient and selective photocatalytic reduction of CO2to CO.Journal of Environmental Chemical Engineering,11(2).

Bian，Songyuan,et al."Bimetal Cu and Fe modified g-C3N4sheets grown on carbon skeleton for efficient and selective photocatalytic reduction of CO2to CO".Journal of Environmental Chemical Engineering 11.2(2023).