Removal of perfluorooctanoic acid by MWCNT-modified carbon-doped titanium dioxide in a peroxymonosulfate/simulated sunlight system

Wang，Yuhan1; Wang，Chao2; Luo，Pei2; Hu，Qing2

2023-03-30

10.1016/j.apsusc.2022.156251

APPLIED SURFACE SCIENCE   影响因子和分区

0169-4332

1873-5584

Perfluorooctanoic acid (PFOA) is widely used as an industrial surfactant and has been detected in various aquatic systems. Herein, a series of multiwalled carbon nanotube (MWCNT)-modified carbon-doped TiO catalysts (xCNT/C-TiO) were prepared through a one-step calcination process and applied as adsorptive photocatalysts. Characterization and density functional theory (DFT) calculation results revealed that carbon doping introduced impurity energy levels between the band structures of TiO. Moreover, the MWCNTs acted as photosensitizers that expanded the wavelength absorption range. The xCNT/C-TiO composites achieved efficient adsorption through multiple pathways (metal-ligand interaction, electrostatic attraction, π-anion interaction, and hydrophobic adsorption), and the adsorbed PFOA was degraded by the simulated sunlight/xCNT/C-TiO/peroxymonosulfate (PMS) systems. The 2CNT/C-TiO sample exhibited the highest PFOA removal efficiency and degraded more than 90 % of the organic contaminant (2 mg/L, defluorination rate of 39.2 %) in 3.5 h. Furthermore, PFOA could be removed during repeated usage of the catalyst system without chemically regenerating the photocatalyst. The enhanced adsorption and photocatalytic removal by xCNT/C-TiO were due to the following reasons: (i) the MWCNTs in the composites provided a different adsorption pathway than the pre-existing monodentate mode and introduced more hydroxyl groups that could adsorb PFOA; (ii) the carbon doping in the TiO lattice reduced the band gap, leading to the more efficient utilization of visible light; (iii) MWCNTs inhibited the recombination of photogenerated charge carriers caused by doping, and this also promoted the production of active species and the direct oxidation of PFOA by photo-induced holes. Finally, enhanced monodentate adsorption mode and photodegradation mechanism were proposed based on experimental results and DFT calculations.

Adsorption pathways Adsorption-induced degradation C-doped TiO2 Monodentate adsorption Perfluorochemicals

SCI ; EI

英语

通讯

National Natural Science Foundation of China["51162026","51909119"] ; Key Projects of the Guangdong Education Department[2021ZDJS081] ; major project of Fundamental and Application Research of the Department of Education of Guangdong Province["2017KZDXM080","2022ZDXM255"]

Chemistry ; Materials Science ; Physics

Chemistry, Physical ; Materials Science, Coatings & Films ; Physics, Applied ; Physics, Condensed Matter

WOS:000923458600001

ELSEVIER

20230113335121

Adsorption ; Catalysts ; Density functional theory ; Energy gap ; Image enhancement ; Multiwalled carbon nanotubes (MWCN) ; Photosensitizers

Light/Optics:741.1 ; Nanotechnology:761 ; Chemical Operations:802.3 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Inorganic Compounds:804.2 ; Probability Theory:922.1 ; Atomic and Molecular Physics:931.3 ; Quantum Theory; Quantum Mechanics:931.4 ; Crystalline Solids:933.1

MATERIALS SCIENCE

2-s2.0-85145259771

Scopus

1.School of Chemistry and Materials Engineering,Huizhou University,Huizhou,Guangdong,516007,China
2.School of Environmental Science and Engineering,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China

Wang，Yuhan,Wang，Chao,Luo，Pei,et al. Removal of perfluorooctanoic acid by MWCNT-modified carbon-doped titanium dioxide in a peroxymonosulfate/simulated sunlight system[J]. APPLIED SURFACE SCIENCE,2023,614.

Wang，Yuhan,Wang，Chao,Luo，Pei,&Hu，Qing.(2023).Removal of perfluorooctanoic acid by MWCNT-modified carbon-doped titanium dioxide in a peroxymonosulfate/simulated sunlight system.APPLIED SURFACE SCIENCE,614.

Wang，Yuhan,et al."Removal of perfluorooctanoic acid by MWCNT-modified carbon-doped titanium dioxide in a peroxymonosulfate/simulated sunlight system".APPLIED SURFACE SCIENCE 614(2023).