Tetranitro-substituted cobalt phthalocyanine immobilized on reduced graphene oxide as supercapacitor electrode material with enhanced capacitance

Qi，Fei1; Wang，Yu1; Xu，Junyuan1; Wang，Xiang1; Wang，Junjie1; Shan，Haiquan1; Li，Minzhang1,2; Xu，Jiaju1

2023-03-01

10.1016/j.synthmet.2023.117284

SYNTHETIC METALS   影响因子和分区

0379-6779

Recent progress in the construction of metal phthalocyanines (MPcs) has opened up new strategies for energy storage applications. Since MPcs possess excellent redox activities, we have developed a simple ultrasound process to fabricate nanocomposites based on different ratios of tetranitro-substituted cobalt phthalocyanine (Co(NO)Pc) and reduced graphene oxide (rGO) and evaluated their energy storage performance for supercapacitor. A maximum specific capacitance of 150.22 F g was achieved for the Co(NO)Pc-rGO 1/6 electrode at high current density (4 A g), which is 1.6 and 1.8 times higher than the individual materials, respectively. This great electrochemical activity is attributed to the synergistic effect between two components. Moreover, this electrode manifested outstanding cycling stability (retained 111.6 % of its initial capacitance after 5000 cycles). The experimental findings ensure the potential application of Co(NO)Pc-rGO composite as an electrode material for the next-generation supercapacitor applications.

Cobalt phthalocyanine Nanocomposite Reduced graphene oxide Specific capacitance

SCI ; EI

英语

第一 ; 通讯

Shenzhen Overseas High-level Talents Innovation Plan of Technical Innovation[KQJSCX20180323140712012]

Materials Science ; Physics ; Polymer Science

Materials Science, Multidisciplinary ; Physics, Condensed Matter ; Polymer Science

WOS:000923013200001

ELSEVIER SCIENCE SA

20230213379459

Capacitance ; Cobalt compounds ; Electrodes ; Energy storage ; Graphene ; Nitrogen oxides ; Supercapacitor

Energy Storage:525.7 ; Electricity: Basic Concepts and Phenomena:701.1 ; Electric Components:704.1 ; Nanotechnology:761 ; Chemical Products Generally:804 ; Inorganic Compounds:804.2 ; Solid State Physics:933

PHYSICS

2-s2.0-85146049638

Scopus

1.Department of Chemistry,Southern University of Science and Technology,Shenzhen,518000,China
2.School of Electronics and Information Engineering,South China Normal University,Foshan,528225,China

Qi，Fei,Wang，Yu,Xu，Junyuan,et al. Tetranitro-substituted cobalt phthalocyanine immobilized on reduced graphene oxide as supercapacitor electrode material with enhanced capacitance[J]. SYNTHETIC METALS,2023,293.

Qi，Fei.,Wang，Yu.,Xu，Junyuan.,Wang，Xiang.,Wang，Junjie.,...&Xu，Jiaju.(2023).Tetranitro-substituted cobalt phthalocyanine immobilized on reduced graphene oxide as supercapacitor electrode material with enhanced capacitance.SYNTHETIC METALS,293.

Qi，Fei,et al."Tetranitro-substituted cobalt phthalocyanine immobilized on reduced graphene oxide as supercapacitor electrode material with enhanced capacitance".SYNTHETIC METALS 293(2023).