Efficient recovery of lithium as Li2CO3 and cobalt as Co3O4 from spent lithium-ion batteries after leaching with p-toluene sulfonic acid

Liu, Jiadong1; Mak, Tsz Yau2; Meng, Zhe1; Wang, Xuyang3; Cao, Yulin3; Lu, Zhouguang3; Suen, Dawson Wai-Shun2; Lu, Xiao-Ying2; Tang, Yuanyuan1

2023-02-01

10.1016/j.hydromet.2022.106012

HYDROMETALLURGY   影响因子和分区

0304-386X

1879-1158

Rechargeable lithium-ion batteries (LIBs) have been widely used in consumer electronics and electric vehicles. In terms of environmental restrictions and circular economy, proper treatment of spent LIBs is of great significance for achieving sustainable development. In this study, organic p-toluene sulfonic acid (PTSA) was employed to recycle valuable Li and Co elements from the spent LIBs for production of battery raw materials (e.g. Li2CO3 and Co3O4). Operation parameters such as PTSA concentration, hydrogen peroxide (H2O2) concentration, solid-to-liquid ratio, leaching temperature and leaching time, were systematically investigated. Under the optimal conditions (0.9 vol% H2O2, 1.5 mol L-1 PTSA, 30 g L-1 solid-to-liquid ratio, 80 degrees C, and 60 min), the leaching efficiencies of commercial LiCoO2 could reach similar to 100% and 99% for Li and Co, respectively, while the corresponding values were about 95% and 93% for the spent LiCoO2. In addition, the selective precipitation of Co-rich compounds in cooled leachate allowed an effective separation of Co from the mixture. The high recovery yield of Co3O4 and Li2CO3 demonstrated the great potential of the PTSA-assisted leaching strategy in hydrometallurgical recycling of the spent LIBs for practical applications. Overall, this proposed recovery process is simple, efficient, and environmentally friendly and is of vital importance for rational treatment of spent LIBs.

Lithium cobalt oxide Recovery P-toluene sulfonic acid Spent lithium-ion battery Kinetics Leaching

SCI ; EI

英语

第一 ; 通讯

National Natural Science Foundation of China[41977329] ; Natural Science Foundation of Guangdong Province["2021B1515020041","2018B030322001"] ; Leading Talents of Guangdong Province Program[2016LJ06C536] ; Guangdong "Climbing" program[pdjh2020a0518] ; Hong Kong Environment and Conservation Fund[39/2019] ; Hong Kong Competitive Research Funding for Faculty Development Scheme[UGC/FDS25/E06/19]

Metallurgy & Metallurgical Engineering

Metallurgy & Metallurgical Engineering

WOS:000916254600001

ELSEVIER

20230113326697

Electronic Waste ; Ions ; Leaching ; Lithium compounds ; Lithium-ion batteries ; Precipitation (chemical) ; Recycling ; Sustainable development ; Toluene

Municipal and Industrial Wastes; Waste Treatment and Disposal:452 ; Industrial Wastes:452.3 ; Chemical Operations:802.3 ; Organic Compounds:804.1

MATERIALS SCIENCE

Web of Science

1.Southern Univ Sci & Technol, Sch Environm Sci & Engn, State Environm Protect Key Lab Integrated Surface, 1088 Xueyuan Ave, Shenzhen 518055, Peoples R China
2.Technol & Higher Educ Inst Hong Kong, Fac Sci & Technol, Hong Kong, Peoples R China
3.Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen Key Lab Interfacial Sci & Engn Mat, 1088 Xueyuan Ave, Shenzhen 518055, Peoples R China

Liu, Jiadong,Mak, Tsz Yau,Meng, Zhe,et al. Efficient recovery of lithium as Li2CO3 and cobalt as Co3O4 from spent lithium-ion batteries after leaching with p-toluene sulfonic acid[J]. HYDROMETALLURGY,2023,216.

Liu, Jiadong.,Mak, Tsz Yau.,Meng, Zhe.,Wang, Xuyang.,Cao, Yulin.,...&Tang, Yuanyuan.(2023).Efficient recovery of lithium as Li2CO3 and cobalt as Co3O4 from spent lithium-ion batteries after leaching with p-toluene sulfonic acid.HYDROMETALLURGY,216.

Liu, Jiadong,et al."Efficient recovery of lithium as Li2CO3 and cobalt as Co3O4 from spent lithium-ion batteries after leaching with p-toluene sulfonic acid".HYDROMETALLURGY 216(2023).