南方科技大学知识苑(SUSTech KC): Second Sphere Effects Promote Formic Acid Dehydrogenation by a Single-Atom Gold Catalyst Supported on Amino-Substituted Graphdiyne

题名	Second Sphere Effects Promote Formic Acid Dehydrogenation by a Single-Atom Gold Catalyst Supported on Amino-Substituted Graphdiyne
作者	Liu, Hong1,2 ; Zou, Haiyuan1,2 ; Wang, Dan1,2 ; Wang, Chuancheng 1,2; Li, Fan1,2 ; Dai, Hao1,2 ; Song, Tao1,2 ; Wang, Mei 4; Ji, Yongfei 3; Duan, Lele1,2
通讯作者	Duan, Lele
发表日期	2023-02-01
DOI	10.1002/anie.202216739
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 影响因子和分区
ISSN	1433-7851
EISSN	1521-3773
卷号	62 期号:11
摘要	Regulating the second sphere of homogeneous molecular catalysts is a common and effective method to boost their catalytic activities, while the second sphere effects have rarely been investigated for heterogeneous single-atom catalysts primarily due to the synthetic challenge for installing functional groups in their second spheres. Benefiting from the well-defined and readily tailorable structure of graphdiyne (GDY), an Au single-atom catalyst on amino-substituted GDY is constructed, where the amino group is located in the second sphere of the Au center. The Au atoms on amino-decorated GDY displayed superior activity for formic acid dehydrogenation compared with those on unfunctionalized GDY. The experimental studies, particularly the proton inventory studies, and theoretical calculations revealed that the amino groups adjacent to an Au atom could serve as proton relays and thus facilitate the protonation of an intermediate Au-H to generate H-2. Our study paves the way to precisely constructing the functional second sphere on single-atom catalysts.
关键词	Catalysis Dehydrogenation Graphdiyne Second Sphere Effect Single-Atom Catalyst
相关链接	[来源记录]
收录类别	SCI ; EI
语种	英语
重要成果	NI论文
学校署名	第一 ; 通讯
资助项目	National Natural Science Foundation of China["22179057","21903016"] ; Stable Support Plan Program of Shenzhen Natural Science Fund[20200925152742003] ; Educational Commission of Guangdong Province[2020KTSCX121]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000920224400001
出版者	WILEY-V C H VERLAG GMBH
EI入藏号	20230513475285
EI主题词	Atoms ; Catalyst activity ; Formic acid ; Gold ; Spheres
EI分类号	Precious Metals:547.1 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Organic Compounds:804.1 ; Atomic and Molecular Physics:931.3
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：22
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/475046
专题	理学院_化学系深圳格拉布斯研究院
作者单位	1.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China 3.Guangzhou Univ, Sch Chem & Chem Engn, Guangzhou 510006, Guangdong, Peoples R China 4.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Peoples R China
第一作者单位	化学系; 深圳格拉布斯研究院
通讯作者单位	化学系; 深圳格拉布斯研究院
第一作者的第一单位	化学系
推荐引用方式 GB/T 7714	Liu, Hong,Zou, Haiyuan,Wang, Dan,et al. Second Sphere Effects Promote Formic Acid Dehydrogenation by a Single-Atom Gold Catalyst Supported on Amino-Substituted Graphdiyne[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2023,62(11).
APA	Liu, Hong.,Zou, Haiyuan.,Wang, Dan.,Wang, Chuancheng.,Li, Fan.,...&Duan, Lele.(2023).Second Sphere Effects Promote Formic Acid Dehydrogenation by a Single-Atom Gold Catalyst Supported on Amino-Substituted Graphdiyne.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,62(11).
MLA	Liu, Hong,et al."Second Sphere Effects Promote Formic Acid Dehydrogenation by a Single-Atom Gold Catalyst Supported on Amino-Substituted Graphdiyne".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 62.11(2023).