Coordination Tailoring of Epitaxial Perovskite-Derived Iron Oxide Films for Efficient Water Oxidation Electrocatalysis

Weng，Zhuanglin1; Huang，Haoliang2; Li，Xiaowen3; Zhang，Yihao1; Shao，Ruiwen4; Yi，Yazhuo1; Lu，Yalin2; Zeng，Xierong1; Zou，Jizhao1; Chen，Lang3; Li，Wei5; Meng，Yuying5; Asefa，Tewodros6; Huang，Chuanwei1

2023-02-17

10.1021/acscatal.2c05147

ACS Catalysis   影响因子和分区

2155-5435

2155-5435

Cost-effective perovskite oxides have recently offered intriguing promise for electrochemical energy storage and conversion systems. Despite the breadth of previously studied electronic structures and properties, the sluggish kinetics of the oxygen evolution reaction (OER) of perovskite oxides basically restrict their applications in metal-air batteries and electrolytic cells. In this work, we report on a highly efficient OER activity of perovskite-derived SrFeO (0.0 ≤ δ ≤ 1.0) single-crystal films by selectively tuning the Fe-O coordination structure and film orientation. Our findings show that the facile anionic oxygen-induced topotactic brownmillerite phase of the SrFeO film possesses superior electrocatalytic performance with a small overpotential and Tafel slope, which is mainly attributed to the peculiar Fe-O coordination framework along with ordered oxygen vacancy channels. Moreover, the low adsorption free energy and small charge transfer resistance could further boost the electrocatalytic OER performance of the (111)-oriented BM-SrFeO films. This delicate tailoring of the epitaxial SrFeO films enables the tunable catalytic reaction pathways and concomitantly efficient OER kinetics, which has significant implications for the rational design of cost-effective and high-performance perovskite-based electrocatalysts.

coordination structure electrocatalysis oxygen evolution reaction perovskite derived oxides single-crystal film topotactic transformation

SCI ; EI

英语

其他

Guangdong Basic and Applied Basic Research Foundation[2019A1515011529] ; National Natural Science Foundation of China[11904372] ; Science and Technology Research Items of Shenzhen[JCYJ20180504165650580] ; Natural Science Foundation of Guangdong Province[2022A1515010211]

Chemistry

Chemistry, Physical

WOS:000935512000001

AMER CHEMICAL SOC

20230713580861

Charge transfer ; Coordination reactions ; Cost effectiveness ; Crystal orientation ; Electrocatalysts ; Electronic structure ; Free energy ; Iron oxides ; Oxide films ; Oxygen ; Oxygen evolution reaction ; Oxygen vacancies ; Perovskite ; Reaction kinetics ; Single crystals

Minerals:482.2 ; Thermodynamics:641.1 ; Electrochemistry:801.4.1 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Inorganic Compounds:804.2 ; Industrial Economics:911.2 ; Crystalline Solids:933.1 ; Crystal Lattice:933.1.1

2-s2.0-85147815943

Scopus

1.Shenzhen Key Laboratory of Special Functional Materials,College of Materials Science and Engineering,Shenzhen University,Shenzhen,518060,China
2.Anhui Laboratory of Advanced Photon Science and Technology,Hefei National Laboratory for Physical Sciences at the Microscale,University of Science and Technology of China,Hefei,Anhui,230026,China
3.Department of Physics,Southern University of Science and Technology,Shenzhen,518055,China
4.Beijing Advanced Innovation Center for Intelligent Robots and Systems,Institute of Convergence in Medicine and Engineering,Beijing Institute of Technology,Beijing,100081,China
5.Institute of Advanced Wear & Corrosion Resistant and Functional Materials,Jinan University,Guangzhou,510632,China
6.Department of Chemistry and Chemical Biology,Department of Chemical and Biochemical Engineering,Rutgers,The State University of New Jersey,Piscataway,610 Taylor Road,08854,United States

Weng，Zhuanglin,Huang，Haoliang,Li，Xiaowen,et al. Coordination Tailoring of Epitaxial Perovskite-Derived Iron Oxide Films for Efficient Water Oxidation Electrocatalysis[J]. ACS Catalysis,2023,13(4):2751-2760.

Weng，Zhuanglin.,Huang，Haoliang.,Li，Xiaowen.,Zhang，Yihao.,Shao，Ruiwen.,...&Huang，Chuanwei.(2023).Coordination Tailoring of Epitaxial Perovskite-Derived Iron Oxide Films for Efficient Water Oxidation Electrocatalysis.ACS Catalysis,13(4),2751-2760.

Weng，Zhuanglin,et al."Coordination Tailoring of Epitaxial Perovskite-Derived Iron Oxide Films for Efficient Water Oxidation Electrocatalysis".ACS Catalysis 13.4(2023):2751-2760.