Covalent Organic Frameworks as Emerging Battery Materials

Wang, Zhiqiang; Hu, Jing; Lu, Zhouguang

2023-02-01

10.1002/batt.202200545

BATTERIES & SUPERCAPS   影响因子和分区

2566-6223

Covalent organic frameworks (COFs) are emerging as promising energy storage materials due to their unique characteristics, such as adjustable thickness, designable topology, superior stability and controllable pore size distribution. Consequently, COFs can provide diversified high-rate carrier transport pathways, and the performance of COFs can be easily improved by adjusting conjugated skeleton types, overlapping p-electron clouds between stacks, and modifying open channels with functional groups. The state-of-the-art COFs electrode materials based on synthetic method and electrochemical performance in recent years are summarized and discussed in this review. The synthesis method, topological structure and application in metal ion (such as Li+, Na+, K+, Zn2+, Mg2+, Al3+, et. al) batteries of COFs electrodes are critically accounted. Finally, we briefly discuss the major challenges in the field that needs to be addressed to pave the way for industrial applications. Although there are still many arduous tasks to be tackled, the burgeoning of COFs-related technologies and applications in batteries provide a ponderable field for commercial process in the short run.

covalent organic framework (COFs) electrochemical performance metal-ion batteries regulate and control topological structure

SCI ; EI

英语

第一 ; 通讯

National Natural Science Foundation of China[21875097] ; Basic Research Project of the Science and Technology Innovation Commission of Shenzhen[JCYJ20200109141640095] ; Shenzhen Key Laboratory of Interfacial Science and Engineering of Materials[ZDSYS20200421111401738]

Electrochemistry ; Materials Science

Electrochemistry ; Materials Science, Multidisciplinary

WOS:000928619800001

WILEY-V C H VERLAG GMBH

20230613561375

Electric batteries ; Electrochemical electrodes ; Pore size ; Topology

Metallurgy:531.1 ; Electric Batteries:702.1 ; Combinatorial Mathematics, Includes Graph Theory, Set Theory:921.4 ; Physical Properties of Gases, Liquids and Solids:931.2 ; Materials Science:951

Web of Science

Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen Key Lab Interfacial Sci & Engn Mat, Shenzhen 518055, Peoples R China

Wang, Zhiqiang,Hu, Jing,Lu, Zhouguang. Covalent Organic Frameworks as Emerging Battery Materials[J]. BATTERIES & SUPERCAPS,2023,6(4).

Wang, Zhiqiang,Hu, Jing,&Lu, Zhouguang.(2023).Covalent Organic Frameworks as Emerging Battery Materials.BATTERIES & SUPERCAPS,6(4).

Wang, Zhiqiang,et al."Covalent Organic Frameworks as Emerging Battery Materials".BATTERIES & SUPERCAPS 6.4(2023).