Antiperovskites with Exceptional Functionalities

Wang, Yonggang1,2; Zhang, Hao1; Zhu, Jinlong2; Lu, Xujie2; Li, Shuai3; Zou, Ruqiang1; Zhao, Yusheng3

2019-12-09

10.1002/adma.201905007

ADVANCED MATERIALS   影响因子和分区

0935-9648

1521-4095

ABX(3) perovskites, as the largest family of crystalline materials, have attracted tremendous research interest worldwide due to their versatile multifunctionalities and the intriguing scientific principles underlying them. Their counterparts, antiperovskites (X(3)BA), are actually electronically inverted perovskite derivatives, but they are not an ignorable family of functional materials. In fact, inheriting the flexible structural features of perovskites while being rich in cations at X sites, antiperovskites exhibit a diverse array of unconventional physical and chemical properties. However, rather less attention has been paid to these "inverse" analogs, and therefore, a comprehensive review is urgently needed to arouse general concern. Recent advances in novel antiperovskite materials and their exceptional functionalities are summarized, including superionic conductivity, superconductivity, giant magnetoresistance, negative thermal expansion, luminescence, and electrochemical energy conversion. In particular, considering the feasibility of the perovskite structure, a universal strategy for enhancing the performance of or generating new phenomena in antiperovskites is discussed from the perspective of solid-state chemistry. With more research enthusiasm, antiperovskites are highly anticipated to become a rising star family of functional materials.

antiperovskites crystal structure functionalities material design

SCI ; EI

英语

通讯

National Key Research and Development Program of China[2017YFA0206701]

Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics

Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter

WOS:000501347200001

WILEY-V C H VERLAG GMBH

20195107853348

Crystallites ; Energy conversion ; Functional materials ; Giant magnetoresistance ; Negative thermal expansion ; Perovskite ; Thermal expansion

Minerals:482.2 ; Energy Conversion Issues:525.5 ; Magnetism: Basic Concepts and Phenomena:701.2 ; Crystalline Solids:933.1 ; Crystal Lattice:933.1.1 ; Materials Science:951

MATERIALS SCIENCE

Web of Science

1.Peking Univ, Coll Engn, Dept Mat Sci & Engn, Beijing Key Lab Adv Battery Mat, Beijing 100871, Peoples R China
2.Ctr High Pressure Sci & Technol Adv Res HPSTAR, Beijing 100094, Peoples R China
3.Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen 518055, Guangdong, Peoples R China

Wang, Yonggang,Zhang, Hao,Zhu, Jinlong,et al. Antiperovskites with Exceptional Functionalities[J]. ADVANCED MATERIALS,2019,32(7).

Wang, Yonggang.,Zhang, Hao.,Zhu, Jinlong.,Lu, Xujie.,Li, Shuai.,...&Zhao, Yusheng.(2019).Antiperovskites with Exceptional Functionalities.ADVANCED MATERIALS,32(7).

Wang, Yonggang,et al."Antiperovskites with Exceptional Functionalities".ADVANCED MATERIALS 32.7(2019).