Enabling good interfacial stability by dual-salt composite electrolyte for long cycle lithium metal batteries

Wang，Qiujun1; Zhang，Pin1; Zhu，Weiqi1; Li，Zhaojin1; Zhang，Di1; Wang，Huan1; Sun，Huilan1; Wang，Bo1; Chi，Shang Sen2

2023-04-30

10.1016/j.jpowsour.2023.232898

JOURNAL OF POWER SOURCES   影响因子和分区

0378-7753

1873-2755

The practical application of solid-state batteries is limited by the relatively low ionic conductivity of solid polymer electrolytes (SPEs) and the high charge transfer resistance resulting from poor interfacial wettability between electrodes and solid electrolytes of inorganic solid electrolytes (ISEs). In this manuscript, a dual-salt dual-network composite electrolyte is prepared by adjusting the content of lithium bis(oxalato)borate (LiBOB) and LiLaZrTaO (LLZTO), and a composite electrolyte with excellent long cycle and interfacial stability is designed. The as-prepared composite electrolyte that includes 77 wt% gel electrolyte, 20 wt% LLZTO and 3 wt% LiBOB (assigned as PDFL-20LLZTO-3LiBOB) has a high ionic conductivity of 1.69 × 10 S cm and a high lithium-ion migration number of 0.833 at 25 °C. The Li metal battery (LMB) with PDFL-20LLZTO-3LiBOB exhibits excellent cycling stability with 94% capacity retention at 25 °C for 100 cycles. The corresponding symmetrical Li|PDFL-20LLZTO-3LiBOB|Li can cycle for over 1200 h with excellent long-term stability. This impressive electrochemical performance is attributed to the in-situ formation of a dense and uniform solid electrolyte interface (SEI) rich in LiF and B–F at the interface under the dual action of LiBOB and fluoroethylene carbonate (FEC). In addition, the high ionic conductivity and high ionic mobility number are favorable for uniform deposition of Li and stable interfacial compatibility.

Composite electrolyte Dual salts In-situ polymerization Lithium metal batteries

SCI ; EI

英语

其他

National Natural Science Foundation of China["22008053","52002111","22279051"] ; Natural Science Foundation of Hebei Province[B2021208061] ; Key Research and Development Program of Hebei Province["20310601D","205A4401D"] ; High Level Talents Funding of Hebei Province[A202005006] ; Science Foundation of University of Hebei Province["BJ2020026","BJ2021001"]

Chemistry ; Electrochemistry ; Energy & Fuels ; Materials Science

Chemistry, Physical ; Electrochemistry ; Energy & Fuels ; Materials Science, Multidisciplinary

WOS:000950226100001

ELSEVIER

20231013677253

Charge transfer ; Ionic conduction in solids ; Lanthanum compounds ; Lithium compounds ; Lithium-ion batteries ; Polyelectrolytes ; Potentiometric sensors ; Solid electrolytes ; Solid state devices ; Solid-State Batteries ; Stability ; Tantalum compounds ; Zirconium compounds

Electricity: Basic Concepts and Phenomena:701.1 ; Secondary Batteries:702.1.2 ; Semiconductor Devices and Integrated Circuits:714.2 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Organic Polymers:815.1.1 ; Polymer Products:817.1

MATERIALS SCIENCE

2-s2.0-85149312463

Scopus

1.Hebei Key Laboratory of Flexible Functional Materials,School of Materials Science and Engineering,Hebei University of Science and Technology,Shijiazhuang,050000,China
2.Department of Materials Science and Engineering,Southern University of Science and Technology (SUSTech),Shenzhen,518055,China

Wang，Qiujun,Zhang，Pin,Zhu，Weiqi,et al. Enabling good interfacial stability by dual-salt composite electrolyte for long cycle lithium metal batteries[J]. JOURNAL OF POWER SOURCES,2023,564.

Wang，Qiujun.,Zhang，Pin.,Zhu，Weiqi.,Li，Zhaojin.,Zhang，Di.,...&Chi，Shang Sen.(2023).Enabling good interfacial stability by dual-salt composite electrolyte for long cycle lithium metal batteries.JOURNAL OF POWER SOURCES,564.

Wang，Qiujun,et al."Enabling good interfacial stability by dual-salt composite electrolyte for long cycle lithium metal batteries".JOURNAL OF POWER SOURCES 564(2023).