Quasi-one-dimensional Ising-like antiferromagnetism in the rare-earth perovskite oxide TbScO3

Zhao, Nan1; Sheng, Jieming1,2; Wang, Jinchen3; Ge, Han1; Li, Tiantian1; Yang, Jiong4; Wang, Shanmin1,5; Miao, Ping6,7; He, Hua8; Tong, Xin9,10; Bao, Wei11; Guo, Er-Jia12,13,14; Mole, Richard15; Yu, Dehong15; Podlesnyak, Andrey A.16; Wu, Liusuo1,5,17

2023-03-02

10.1103/PhysRevMaterials.7.034401

Physical Review Materials   影响因子和分区

2475-9953

The rare-earth perovskite TbScO3 has been widely used as a substrate for the growth of epitaxial ferroelectric and multiferroic thin films, while its detailed low-temperature magnetic properties were rarely reported. In this paper, we performed detailed magnetization, specific heat, and single crystal neutron scattering measurements, along with the crystalline electric field calculations to study the low-temperature magnetic properties of TbScO3. All our results suggest the magnetic Tb3+ has an Ising-like pseudo-doublet ground state at low temperatures. Due to the constrain of local point symmetry, these Tb3+ Ising moments are confined in the ab plane with a tilt angle of phi = +/- 48 degrees to the a axis. In zero field, the system undergoes an antiferromagnetic phase transition at T-N = 2.53 K, and forms a G(x)A(y) noncollinear magnetic structure below T-N. We find the dipole-dipole interactions play an important role to determine the magnetic ground state, which are also responsible for the quasi-one-dimensional magnetism in TbScO3. The significant anisotropic diffuse scatterings further confirm the quasi-one-dimensional magnetism along the c axis. The magnetic phase diagram with the field along the easy b axis is well established. In addition to the G(x)A(y) antiferromagnetic state, there is an exotic field-induced phase emerged near the critical field B-c similar or equal to 0.7 T, where three-dimensional magnetic order is suppressed but strong one-dimensional correlations may still exist.

SCI ; EI

英语

第一 ; 通讯

National Key Research and Development Program of China[12134020] ; National Natural Science Foundation of China["11974157","12174175","12004426","12005243","12104255","JCYJ20220818100405013"] ; Shenzhen Fundamental Research Program[2021B1515120015] ; Guangdong Basic and Applied Basic Research Foundation["2022B1515120014","ZDSYS20190902092905285"] ; Shenzhen Key Laboratory of Advanced Quantum Functional Materials and Devices[11227906] ; National Key Scientific Instrument and Equipment Development Project of NSFC[KQTD20200820113047086] ; null[2021YFA1400400]

Materials Science

Materials Science, Multidisciplinary

WOS:000944113700002

AMER PHYSICAL SOC

20231413847128

Antiferromagnetism ; Electric fields ; Ferroelectric films ; Ferroelectricity ; Ground state ; Magnetic properties ; Neutron scattering ; Phase diagrams ; Rare earths ; Single crystals ; Specific heat ; Temperature ; Terbium compounds ; Thin films

Minerals:482.2 ; Thermodynamics:641.1 ; Electricity: Basic Concepts and Phenomena:701.1 ; Magnetism: Basic Concepts and Phenomena:701.2 ; Dielectric Materials:708.1 ; Inorganic Compounds:804.2 ; Crystalline Solids:933.1

Web of Science

1.Southern Univ Sci & Technol, Dept Phys, Shenzhen 518055, Peoples R China
2.Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen 518055, Peoples R China
3.Renmin Univ China, Dept Phys, Beijing 100872, Peoples R China
4.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China
5.Quantum Sci Ctr Guangdong Hong Kong Macao Greater, Shenzhen 518045, Peoples R China
6.Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China
7.Spallat Neutron Source Sci Ctr, Dongguan 523803, Peoples R China
8.Univ Chinese Acad Sci UCAS, Sch Chem Sci, Beijing 100190, Peoples R China
9.Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China
10.China Spallat Neutron Source CSNS, Dongguan 523803, Peoples R China
11.City Univ Hong Kong, Dept Phys, Hong Kong 999077, Peoples R China
12.Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
13.Univ Chinese Acad Sci, Ctr Mat Sci & Optoelect Engn, Sch Phys Sci, Beijing 100049, Peoples R China
14.Songshan Lake Mat Lab, Dongguan 523808, Guangdong, Peoples R China
15.Australian Nucl Sci & Technol Org, Lucas Heights, NSW 2234, Australia
16.Oak Ridge Natl Lab, Neutron Scattering Div, Oak Ridge, TN 37831 USA
17.Southern Univ Sci & Technol, Shenzhen Key Lab Adv Quantum Funct Mat & Devices, Shenzhen 518055, Peoples R China

Zhao, Nan,Sheng, Jieming,Wang, Jinchen,et al. Quasi-one-dimensional Ising-like antiferromagnetism in the rare-earth perovskite oxide TbScO3[J]. Physical Review Materials,2023,7(3).

Zhao, Nan.,Sheng, Jieming.,Wang, Jinchen.,Ge, Han.,Li, Tiantian.,...&Wu, Liusuo.(2023).Quasi-one-dimensional Ising-like antiferromagnetism in the rare-earth perovskite oxide TbScO3.Physical Review Materials,7(3).

Zhao, Nan,et al."Quasi-one-dimensional Ising-like antiferromagnetism in the rare-earth perovskite oxide TbScO3".Physical Review Materials 7.3(2023).