南方科技大学知识苑(SUSTech KC): Rational design of septenary high-entropy alloy for direct ethanol fuel cells

题名	Rational design of septenary high-entropy alloy for direct ethanol fuel cells
作者	Chang, Jinfa 1; Wang, Guanzhi 1,4; Li, Cheng2,7 ; He, Yaqi2 ; Zhu, Yuanmin2 ; Zhang, Wei 1,4; Sajid, Muhammad 3; Kara, Abdelkader 3,5; Gu, Meng2 ; Yang, Yang 1,4,5,6,8
通讯作者	Yang, Yang
发表日期	2023-03-15
DOI	10.1016/j.joule.2023.02.011
发表期刊	Joule 影响因子和分区
ISSN	2542-4351
EISSN	2542-4351
卷号	7 期号:3页码:587-602
摘要	Promoting C–C bond cleavage of ethanol by a complete 12-electron (12e) ethanol oxidation reaction (EOR) is a grand challenge for the development of highly efficient direct ethanol fuel cells (DEFCs). Most state-of-the-art catalysts only implement the EOR in an incomplete 4e or 2e pathway because of the poisoning of the catalysts by strongly adsorbed CO, leading to the poor output performance and low cell efficiency of DEFCs. Herein, a septenary PtPdFeCoNiSnMn high-entropy alloy (PtPd HEA) with a PtPd-rich surface but super-low platinum group metals loading was developed. We identified and proved the functions of each element in the PtPd HEA. The DEFCs assembled with the PtPd HEA (0.12 mgPtPd.cm⁻²) achieved a maximum power density of 0.72 W cm⁻² and a durable operation for 1,200 h, which outperforms state-of-the-art catalysts for DEFCs. This work will be a design principle for nanostructured alloy development for renewable energy and sustainability applications. © 2023 Elsevier Inc.
相关链接	[来源记录]
收录类别	EI ; SCI
语种	英语
重要成果	ESI高被引
学校署名	其他
资助项目	This work was supported by the University of Central Florida (UCF). J.C. acknowledges the financial support from the Preeminent Postdoctoral Program (P3) at UCF. The XPS test was supported by the NSF MRI: XPS: ECCS: 1726636, hosted in MCF-AMPAC facility, MSE, CECS, UCF. M.G. acknowledges support from the National Key Research and Development Project (2022YFA1503900), the Shenzhen fundamental research funding (JCYJ20210324115809026, 20200925154115001, and JCYJ20200109141216566), Shenzhen Science and Technology Program (grant no. KQTD20190929173815000), and Guangdong Innovative and Entrepreneurial Research Team Program (grant no. 2019ZT08C044). M.G. also thanks the Pico Center at SUSTech CRF that receives support from Presidential fund and Development and Reform Commission of Shenzhen Municipality. A.K. acknowledges support from donors of the American Chemical Society Petroleum Research Fund for support (or partial support) of this research. This research used resources from the National Energy Research Scientific Computing Center (NERSC), which is supported by the Office of Science of the US Department of Energy. Y.Y. led the project. J.C. performed most of the experiments and analyzed most of the data. G.W. performed the XRD and XPS characterizations. C.L. Y.Z. and M.G. took and analyzed the TEM. Y.H. performed the ICP test. W.Z. performed and analyzed the 1H NMR data. M.S. and A.K. performed the DFT calculations. J.C. G.W. and Y.Y. drafted the paper. All the authors discussed the results and revised the paper together. The high-entropy alloy fuel cell catalysts disclosed in this work have been filed as US Provisional Patent Application (Serial no. 63/388,085) with Y.Y. and J.C. as inventors. The status of the patent application is pending.This work was supported by the University of Central Florida (UCF). J.C. acknowledges the financial support from the Preeminent Postdoctoral Program (P3) at UCF. The XPS test was supported by the NSF MRI: XPS: ECCS : 1726636 , hosted in MCF-AMPAC facility, MSE, CECS, UCF. M.G. acknowledges support from the National Key Research and Development Project ( 2022YFA1503900 ), the Shenzhen fundamental research funding ( JCYJ20210324115809026 , 20200925154115001 , and JCYJ20200109141216566 ), Shenzhen Science and Technology Program (grant no. KQTD20190929173815000 ), and Guangdong Innovative and Entrepreneurial Research Team Program (grant no. 2019ZT08C044 ). M.G. also thanks the Pico Center at SUSTech CRF that receives support from Presidential fund and Development and Reform Commission of Shenzhen Municipality . A.K. acknowledges support from donors of the American Chemical Society Petroleum Research Fund for support (or partial support) of this research. This research used resources from the National Energy Research Scientific Computing Center (NERSC), which is supported by the Office of Science of the US Department of Energy.
WOS研究方向	Chemistry ; Energy & Fuels ; Materials Science
WOS类目	Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS记录号	WOS:000955390600001
出版者	Cell Press
EI入藏号	20231113735751
EI主题词	Binary alloys ; Catalyst poisoning ; Cobalt alloys ; Direct ethanol fuel cells (DEFC) ; Electrolytic reduction ; Entropy ; Ethanol fuels ; High-entropy alloys ; Iron alloys ; Manganese alloys ; Oxygen ; Palladium alloys
EI分类号	Liquid Fuels:523 ; Metallurgy and Metallography:531 ; Ore Treatment:533.1 ; Chromium and Alloys:543.1 ; Manganese and Alloys:543.2 ; Iron Alloys:545.2 ; Precious Metals:547.1 ; Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals:549.3 ; Thermodynamics:641.1 ; Fuel Cells:702.2 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Organic Compounds:804.1
来源库	EV Compendex
引用统计	被引频次[WOS]：49
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/519636
专题	工学院_材料科学与工程系
作者单位	1.NanoScience Technology Center, University of Central Florida, Orlando; FL; 32826, United States 2.Department of Materials Science and Engineering, Southern University of Science and Technology, Shenzhen; 518055, China 3.Department of Physics, University of Central Florida, Orlando; FL; 32816, United States 4.Department of Materials Science and Engineering, University of Central Florida, Orlando; FL; 32826, United States 5.Renewable Energy and Chemical Transformation Cluster, University of Central Florida, Orlando; FL; 32826, United States 6.Department of Chemistry, University of Central Florida, Orlando; FL; 32826, United States 7.School of Physics and Astronomy, University of Birmingham, Birmingham; B15 2TT, United Kingdom 8.The Stephen W. Hawking Center for Microgravity Research and Education, University of Central Florida, Orlando; FL; 32826, United States
推荐引用方式 GB/T 7714	Chang, Jinfa,Wang, Guanzhi,Li, Cheng,et al. Rational design of septenary high-entropy alloy for direct ethanol fuel cells[J]. Joule,2023,7(3):587-602.
APA	Chang, Jinfa.,Wang, Guanzhi.,Li, Cheng.,He, Yaqi.,Zhu, Yuanmin.,...&Yang, Yang.(2023).Rational design of septenary high-entropy alloy for direct ethanol fuel cells.Joule,7(3),587-602.
MLA	Chang, Jinfa,et al."Rational design of septenary high-entropy alloy for direct ethanol fuel cells".Joule 7.3(2023):587-602.