南方科技大学知识苑(SUSTech KC): Our Voyage from Catalytic Cross-Hydroalkenylation to Transfer-Dehydroaromatization of Cyclic pi-Systems: Reactivity and Selectivity Changes Enabled by NHC-Ni and NHC-Pd Hydride Equivalents

题名	Our Voyage from Catalytic Cross-Hydroalkenylation to Transfer-Dehydroaromatization of Cyclic pi-Systems: Reactivity and Selectivity Changes Enabled by NHC-Ni and NHC-Pd Hydride Equivalents
作者	Chen, Yang1,2,3 ; Chen, Weihao1,2,3 ; Gu, Xiao1,2,3 ; Ho, Chun-Yu1,2,3
通讯作者	Ho, Chun-Yu
发表日期	2023-03-01
DOI	10.1055/s-0042-1751425
发表期刊	SYNLETT 影响因子和分区
ISSN	0936-5214
EISSN	1437-2096
卷号	34 期号:14
摘要	N-Heterocyclic carbene ligated transition-metal catalysts often show interesting properties and reactivity as compared to conventional ligand systems. In (NHC)Ni and (NHC)Pd hydrides, a dramatic reactivity changed from cross-hydroalkenylation to transfer-dehydroaromatization was observed under optimized conditions. This account summarizes our recent efforts and stories behind this serendipitous discovery. The mechanistic studies revealed that the keys to divert the desired reactivity are the differences in the olefin insertion selectivity and the hydrometallated species reactivity.
关键词	hydroalkenylation transfer-hydrogenation dehydroaromatization N-heterocyclic carbenes nickel palladium
相关链接	[来源记录]
收录类别	SCI
语种	英语
学校署名	第一 ; 通讯
资助项目	Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; Southern University of Science and Technology (SUSTech)["Y01501808","Y01506014"] ; National Natural Science Foundation of China (NSFC)[22071096]
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:000948838800003
出版者	GEORG THIEME VERLAG KG
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：1
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/523895
专题	深圳格拉布斯研究院理学院_化学系
作者单位	1.Southern Univ Sci &Technol SUSTech, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China 2.Southern Univ Sci &Technol SUSTech, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China 3.Southern Univ Sci &Technol SUSTech, Dept Chem, Shenzhen 518055, Peoples R China
第一作者单位	南方科技大学; 深圳格拉布斯研究院; 化学系
通讯作者单位	南方科技大学; 深圳格拉布斯研究院; 化学系
第一作者的第一单位	南方科技大学
推荐引用方式 GB/T 7714	Chen, Yang,Chen, Weihao,Gu, Xiao,et al. Our Voyage from Catalytic Cross-Hydroalkenylation to Transfer-Dehydroaromatization of Cyclic pi-Systems: Reactivity and Selectivity Changes Enabled by NHC-Ni and NHC-Pd Hydride Equivalents[J]. SYNLETT,2023,34(14).
APA	Chen, Yang,Chen, Weihao,Gu, Xiao,&Ho, Chun-Yu.(2023).Our Voyage from Catalytic Cross-Hydroalkenylation to Transfer-Dehydroaromatization of Cyclic pi-Systems: Reactivity and Selectivity Changes Enabled by NHC-Ni and NHC-Pd Hydride Equivalents.SYNLETT,34(14).
MLA	Chen, Yang,et al."Our Voyage from Catalytic Cross-Hydroalkenylation to Transfer-Dehydroaromatization of Cyclic pi-Systems: Reactivity and Selectivity Changes Enabled by NHC-Ni and NHC-Pd Hydride Equivalents".SYNLETT 34.14(2023).