| 题名 | Alkoxyphosphorane/Borane Cooperative Alkylations: A Frustrated Lewis Pair Version of the Mitsunobu Reaction |
| 作者 | |
| 通讯作者 | Liu, Liu Leo; Wu, Yile; Stephan, Douglas W. |
| 发表日期 | 2023-03-01
|
| DOI | |
| 发表期刊 | |
| ISSN | 0947-6539
|
| EISSN | 1521-3765
|
| 卷号 | 29 |
| 摘要 | The combination of the alkoxyphosphoranes, Ph2P(OR)(O2C6Cl4) and the borane B(C6F5)(3) generates the zwitterions 3 which act as FLP to effect the alkylation of several nucleophiles affording C-C, C-N, C-H and C-Cl coupling products. A DFT study shows the reaction proceeds via an FLP activation pathway generating an alkoxyphosphonium intermediate which effects the alkylation of the nucleophiles, akin to the Mitsunobu reaction. |
| 关键词 | |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 学校署名 | 通讯
|
| 资助项目 | Ningbo Natural Science Foundation[2022J108]
; Scientific Research Grant of Ningbo University["215-432000282","422110973"]
; Ningbo Top Talent Project[215-432094250]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Multidisciplinary
|
| WOS记录号 | WOS:000949017400001
|
| 出版者 | |
| EI入藏号 | 20231113741918
|
| EI主题词 | Chlorine compounds
; Nucleophiles
; Reaction intermediates
|
| EI分类号 | Chemical Reactions:802.2
; Chemical Products Generally:804
|
| ESI学科分类 | CHEMISTRY
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：1
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/523904 |
| 专题 | 理学院_化学系 |
| 作者单位 | 1.Ningbo Univ, Inst Drug Discovery Technol, Ningbo 315211, Zhejiang, Peoples R China 2.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China 4.Univ Toronto, Dept Chem, 80 St George St, Toronto, ON M5S 3H6, Canada |
| 通讯作者单位 | 化学系; 南方科技大学 |
| 推荐引用方式 GB/T 7714 |
Chen, Ting,Mei, Yanbo,Liu, Liu Leo,et al. Alkoxyphosphorane/Borane Cooperative Alkylations: A Frustrated Lewis Pair Version of the Mitsunobu Reaction[J]. CHEMISTRY-A EUROPEAN JOURNAL,2023,29.
|
| APA |
Chen, Ting,Mei, Yanbo,Liu, Liu Leo,Zhao, Yufen,Wu, Yile,&Stephan, Douglas W..(2023).Alkoxyphosphorane/Borane Cooperative Alkylations: A Frustrated Lewis Pair Version of the Mitsunobu Reaction.CHEMISTRY-A EUROPEAN JOURNAL,29.
|
| MLA |
Chen, Ting,et al."Alkoxyphosphorane/Borane Cooperative Alkylations: A Frustrated Lewis Pair Version of the Mitsunobu Reaction".CHEMISTRY-A EUROPEAN JOURNAL 29(2023).
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| 条目包含的文件 | 条目无相关文件。 | |||||
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