南方科技大学知识苑(SUSTech KC): Facile preparation of tetrafluoro-substituted cobalt phthalocyanine nanorods attached on carbon nanotubes for efficient electrocatalytic CO2 reduction

题名	Facile preparation of tetrafluoro-substituted cobalt phthalocyanine nanorods attached on carbon nanotubes for efficient electrocatalytic CO2 reduction
作者	Li, Minzhang1 ; Xu, Junyuan 1; Qi, Fei1 ; Wang, Yu1 ; Yan, Chunliu2 ; Xu, Jiaju1
通讯作者	Xu, Jiaju
发表日期	2023-03-01
DOI	10.1007/s10008-023-05480-3
发表期刊	JOURNAL OF SOLID STATE ELECTROCHEMISTRY 影响因子和分区
ISSN	1432-8488
EISSN	1433-0768
卷号	27 期号:5页码:1269-1278
摘要	A tetrafluoro substituted CoPc (CoF4Pc), which is well dispersed in N,N-dimethylformamide (DMF), was used to modify carbon nanotubes (CNTs) via a facile sonication method, resulting in CoF4Pc nanorods with the length lower than 30 nm on the CNT surface. The as-fabricated CoF4Pc-CNT composites showed superior CO2RR catalytic activity compared with that of individual CoF4Pc, due to enhanced mass transfer and electrical conductivity arising from the CNT substrate. The CoF4Pc-CNT composite with the CoF4Pc/CNT weight ratio of 2:30 exhibited the highest CO current density of 29.0 mA cm(-2) and CO selectivity of 91.8% at - 0.85 V vs. reversible hydrogen electrode (RHE) in a flow cell setup containing 0.5 M KHCO3, which was ascribed to enhanced charge transfer induced by highly dispersion of CoF4Pc nanorods, and good conductivity of CNT substrates. The work provides new insights for developing low-cost, effective, phthalocyanine-based catalysts for electrochemical CO2RR.
关键词	Electrocatalysis Cobalt phthalocyanine Carbon nanotubes Nanocomposite CO2 reduction
相关链接	[来源记录]
收录类别	SCI ; EI
语种	英语
学校署名	第一 ; 通讯
WOS研究方向	Electrochemistry
WOS类目	Electrochemistry
WOS记录号	WOS:000956949900001
出版者	SPRINGER
EI入藏号	20231413845441
EI主题词	Carbon dioxide ; Carbon nanotubes ; Charge transfer ; Cobalt ; Electrocatalysis ; Mass transfer ; Nanorods ; Organic solvents ; Potassium compounds ; Reduction ; Substrates
EI分类号	Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals:549.3 ; Mass Transfer:641.3 ; Nanotechnology:761 ; Electrochemistry:801.4.1 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Organic Compounds:804.1 ; Inorganic Compounds:804.2 ; Solid State Physics:933 ; Crystalline Solids:933.1
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：5
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/523934
专题	理学院_化学系工学院_深港微电子学院
作者单位	1.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Sch Microelect, Shenzhen 518055, Peoples R China
第一作者单位	化学系
通讯作者单位	化学系
第一作者的第一单位	化学系
推荐引用方式 GB/T 7714	Li, Minzhang,Xu, Junyuan,Qi, Fei,et al. Facile preparation of tetrafluoro-substituted cobalt phthalocyanine nanorods attached on carbon nanotubes for efficient electrocatalytic CO2 reduction[J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY,2023,27(5):1269-1278.
APA	Li, Minzhang,Xu, Junyuan,Qi, Fei,Wang, Yu,Yan, Chunliu,&Xu, Jiaju.(2023).Facile preparation of tetrafluoro-substituted cobalt phthalocyanine nanorods attached on carbon nanotubes for efficient electrocatalytic CO2 reduction.JOURNAL OF SOLID STATE ELECTROCHEMISTRY,27(5),1269-1278.
MLA	Li, Minzhang,et al."Facile preparation of tetrafluoro-substituted cobalt phthalocyanine nanorods attached on carbon nanotubes for efficient electrocatalytic CO2 reduction".JOURNAL OF SOLID STATE ELECTROCHEMISTRY 27.5(2023):1269-1278.