batP2dFoam: An Efficient Segregated Solver for the Pseudo-2-Dimensional (P2D) Model of Li-Ion Batteries

Yin，Xiaoguang1,2; Zhang，Dongxiao1,3

2023-03-01

10.1149/1945-7111/acbfe4

Journal of the Electrochemical Society   影响因子和分区

0013-4651

1945-7111

An efficient solver for the pseudo-2-dimensional (P2D) model of Li-ion batteries is developed based on the open-source computational fluid dynamics platform OpenFOAM. Species and charge conservation equations are solved in a segregated manner: potential and concentration of electrolyte and solid electrode are solved sequentially. The non-linearity and interlinkage are handled by an iterative procedure. In the P2D model, solving Li-ion (de)intercalation in solid particles implicitly is time-consuming. The Picard method is employed for calculating solid concentration explicitly without the need to solve the discretized equations system. In one time step, Li-ion concentration of future time is recursively approximated until convergence. The explicit solving of solid concentration in combination with the overall iterative procedure makes solving of the P2D model efficient. Nonlinear source terms are linearized whenever possible to retain stability. Adaptive time-stepping is devised, grounded on the derivative of open circuit voltage (OCV) with regard to Li-ion concentration at the particle surface. The developed solver is validated in detail with respect to COMSOL. Performance under various operation conditions, such as discharge of rate 10 C, hybrid charge-discharge cycle, and urban dynamometer driving schedule (UDDS), demonstrates its robustness.

OpenFOAM P2D model Picard method Porous electrode theory Segregated solver

SCI ; EI

英语

第一 ; 通讯

National Natural Science Foundation of China[12102170] ; Shenzhen Key Laboratory of Natural Gas Hydrates[ZDSYS20200421111201738]

Electrochemistry ; Materials Science

Electrochemistry ; Materials Science, Coatings & Films

WOS:000949360700001

ELECTROCHEMICAL SOC INC

20231313803775

Cathodes ; Computation theory ; Computational fluid dynamics ; Conservation ; Electric discharges ; Electrolytes ; Ions ; Iterative methods ; Open circuit voltage

Electricity: Basic Concepts and Phenomena:701.1 ; Electric Batteries and Fuel Cells:702 ; Computer Theory, Includes Formal Logic, Automata Theory, Switching Theory, Programming Theory:721.1 ; Computer Applications:723.5 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Numerical Methods:921.6 ; Mechanics:931.1

CHEMISTRY

2-s2.0-85150761017

Scopus

1.National Center for Applied Mathematics Shenzhen (NCAMS),Southern University of Science and Technology,Shenzhen,518055,China
2.School of Environmental Science and Engineering,Southern University of Science and Technology,Shenzhen,518055,China
3.Department of Mathematics and Theories,Peng Cheng Laboratory,Shenzhen,518000,China

Yin，Xiaoguang,Zhang，Dongxiao. batP2dFoam: An Efficient Segregated Solver for the Pseudo-2-Dimensional (P2D) Model of Li-Ion Batteries[J]. Journal of the Electrochemical Society,2023,170(3).

Yin，Xiaoguang,&Zhang，Dongxiao.(2023).batP2dFoam: An Efficient Segregated Solver for the Pseudo-2-Dimensional (P2D) Model of Li-Ion Batteries.Journal of the Electrochemical Society,170(3).

Yin，Xiaoguang,et al."batP2dFoam: An Efficient Segregated Solver for the Pseudo-2-Dimensional (P2D) Model of Li-Ion Batteries".Journal of the Electrochemical Society 170.3(2023).