Low-Concentration Redox-Electrolytes for High-Rate and Long-Life Zinc Metal Batteries

Wang，Shipeng1; Zhao，Yuwei2; Lv，Haiming2; Hu，Xuanhe1; He，Jun1; Zhi，Chunyi2; Li，Hongfei2,3

2023

10.1002/smll.202207664

Small   影响因子和分区

1613-6810

1613-6829

The uncontrolled zinc electrodeposition and side reactions severely limit the power density and lifespan of Zn metal batteries. Herein, the multi-level interface adjustment effect is realized with low-concentration redox-electrolytes (0.2 m KI) additives. The iodide ions adsorbed on the zinc surface significantly suppress water-induced side reactions and by-product formation and enhance the kinetics of zinc deposition. The distribution of relaxation times results reveal that iodide ions can reduce the desolvation energy of hydrated zinc ions and guide the deposition of zinc ions due to their strong nucleophilicity. As a consequence, the Zn||Zn symmetric cell achieves superior cycling stability (>3000 h at 1 mA cm, 1 mAh cm) accompanied by a uniform deposition and a fast reaction kinetics with a low voltage hysteresis (<30 mV). Additionally, coupled with an activated carbon (AC) cathode, the assembled Zn||AC cell delivers a high-capacity retention of 81.64% after 2000 cycles at 4 A g. More importantly, the operando electrochemical UV–vis spectroscopies show that a small number of I can spontaneously react with the dead zinc as well as basic zinc saltsand regenerate iodide ions and zinc ions; thus, the Coulombic efficiency of each charge–discharge process is close to 100%.

aqueous zinc batteries basic zinc salts distribution of relaxation times iodide electrolytes redox-electrolytes

SCI ; EI

英语

通讯

National Natural Science Foundation of China[22005207] ; Guangdong Basic and Applied Basic Research Foundation["2021B1515120004","2022A0505050015"]

Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics

Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter

WOS:000963528700001

WILEY-V C H VERLAG GMBH

20231513863872

Activated carbon ; Additives ; Deposition ; Electric discharges ; Electrodes ; Ions ; Reaction kinetics ; Relaxation time ; Salts ; Zinc

Zinc and Alloys:546.3 ; Electricity: Basic Concepts and Phenomena:701.1 ; Electric Batteries and Fuel Cells:702 ; Chemical Reactions:802.2 ; Chemical Operations:802.3 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Classical Physics; Quantum Theory; Relativity:931

2-s2.0-85151735571

Scopus

1.School of Chemical Engineering and Light Industry,Guangdong University of Technology,Guangzhou,Guangdong,510006,China
2.Songshan Lake Materials Laboratory,Dongguan,Guangdong,523808,China
3.School of System Design and Intelligent Manufacturing,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China

Wang，Shipeng,Zhao，Yuwei,Lv，Haiming,et al. Low-Concentration Redox-Electrolytes for High-Rate and Long-Life Zinc Metal Batteries[J]. Small,2023.

Wang，Shipeng.,Zhao，Yuwei.,Lv，Haiming.,Hu，Xuanhe.,He，Jun.,...&Li，Hongfei.(2023).Low-Concentration Redox-Electrolytes for High-Rate and Long-Life Zinc Metal Batteries.Small.

Wang，Shipeng,et al."Low-Concentration Redox-Electrolytes for High-Rate and Long-Life Zinc Metal Batteries".Small (2023).