Approaching the theoretical efficiency limit of quantum-dot light-emitting diodes via synergistic optimization

Li，Haotao; Tian，Fengshou; Chen，Shuming

2023

10.1007/s12274-023-5520-6

Nano Research   影响因子和分区

1998-0124

1998-0000

The importance of optical resonance in enhancing light outcoupling efficiency (OCE) is frequently overlooked in conventional bottom-emitting quantum-dot light-emitting diodes (QLEDs) due to their weak microcavity effect. Herein, we show that by synergistically optimizing the optical and the electrical performances, QLEDs with efficiency approaching the theoretical limit can be realized. By introducing a high refractive index indium zinc oxide (IZO) electrode and optimizing its thickness, the light OCE is significantly improved and consequently the red QLEDs exhibit an external quantum efficiency (EQE) of 33.2%, which is 1.4-fold higher than that of the reference devices with conventional indium tin oxide (ITO) electrodes. Moreover, with a high refractive index plastic substrate and a microlens array, the EQE can further be improved to a record value of 37.5%. Similar results are obtained in green and blue devices, which show an EQE of 18.8% and 14.4%, respectively. We also predict that the theoretical EQE limit of red, green, and blue QLEDs can reach 35.4%–36.5%, 24.8%–34.0%, and 25.1%–35.8%, respectively, without using any light outcoupling structures. The proposed synergistic optimization strategy enables the efficiencies of red, green, and blue QLEDs to approach their theoretical limits. [Figure not available: see fulltext.]

light outcoupling efficiency light-emitting diodes microcavity quantum dots theoretically maximal efficiency

SCI ; EI

英语

第一 ; 通讯

National Natural Science Foundation of China[62174075] ; Shenzhen Science and Technology Program["JCYJ20210324105400002","JCYJ20220530113809022"] ; Guangdong University Research Program[2020ZDZX3062]

Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics

Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied

WOS:000962371900008

TSINGHUA UNIV PRESS

20231413850837

Electrodes ; II-VI semiconductors ; Nanocrystals ; Organic light emitting diodes (OLED) ; Quantum efficiency ; Quantum optics ; Refractive index ; Semiconductor quantum dots ; Tin oxides ; Zinc oxide

Semiconducting Materials:712.1 ; Electronic Components and Tubes:714 ; Semiconductor Devices and Integrated Circuits:714.2 ; Light/Optics:741.1 ; Nanotechnology:761 ; Inorganic Compounds:804.2 ; Quantum Theory; Quantum Mechanics:931.4 ; Crystalline Solids:933.1

2-s2.0-85151488312

Scopus

Department of Electrical and Electronic Engineering,Southern University of Science and Technology,Shenzhen,518055,China

Li，Haotao,Tian，Fengshou,Chen，Shuming. Approaching the theoretical efficiency limit of quantum-dot light-emitting diodes via synergistic optimization[J]. Nano Research,2023,16(7):10156-10163.

Li，Haotao,Tian，Fengshou,&Chen，Shuming.(2023).Approaching the theoretical efficiency limit of quantum-dot light-emitting diodes via synergistic optimization.Nano Research,16(7),10156-10163.

Li，Haotao,et al."Approaching the theoretical efficiency limit of quantum-dot light-emitting diodes via synergistic optimization".Nano Research 16.7(2023):10156-10163.