Recent Progress on Synthesis, Intrinsic Properties and Optoelectronic Applications of Perovskite Single Crystals

Li，Huayang1; Shen，Nan1; Chen，Shi1; Guo，Fei2; Xu，Baomin3

2023

10.1002/adfm.202214339

Advanced Functional Materials   影响因子和分区

1616-301X

1616-3028

Metal halide perovskite have shown great potential for applications in photovoltaics, light-emitting diodes and photon detectors, mainly owing to their superb optoelectronic properties, low-cost raw materials and facile fabrication process. Although, polycrystalline perovskite thin-films have been actively investigated for preparing various optoelectronic devices, the presence of detrimental defects at grain boundaries, serious ion migration and limited stability unfortunately hinder their device performance and practical application. As a contrast, perovskite single crystals (SCs) exhibit no grain boundaries, much lower trap density and much improved stability, hence providing a more attractive choice for not only optoelectronic device applications but also fundamental research. In this review, recent progress in the growth methods of perovskite SCs is summarized, followed by giving a detailed introduction of the intrinsic properties of perovskite SCs including optical properties, defects, charge carrier dynamics, ion migration and stability. On these base, the applications of perovskite SCs in various optoelectronic devices like solar cells, photodetectors, and radiation detectors are discussed, where the relationship between the composition, device architecture and device performance is highlighted. Finally, a tentative discussion on the current challenges and future opportunities in the development of perovskite SCs and optoelectronic devices is presented.

growth methods intrinsic properties optoelectronic applications perovskite single crystals

SCI ; EI

英语

通讯

National Natural Science Foundation of China[62004089] ; Special Zone Support Program for Outstanding Talents of Henan University[CX3050A0970530] ; National Key Research and Development project["2021YFB3800100","2021YFB3800101"] ; Basic and Applied Basic Research Foundation of Guangdong Province[2019B1515120083]

Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics

Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter

WOS:000951696800001

WILEY-V C H VERLAG GMBH

20231313812021

Grain boundaries ; Metal halides ; Optical properties ; Optoelectronic devices ; Perovskite solar cells ; Photons ; Radiation detectors ; Single crystals

Minerals:482.2 ; Solar Cells:702.3 ; Light/Optics:741.1 ; Optical Devices and Systems:741.3 ; Chemical Products Generally:804 ; Atomic and Molecular Physics:931.3 ; Crystalline Solids:933.1 ; Radiation Measuring Instruments:944.7

MATERIALS SCIENCE

2-s2.0-85150878401

Scopus

1.Henan Key Laboratory of Photovoltaic Materials,Henan University,Kaifeng,475004,China
2.Institute of New Energy Technology,College of Information Science and Technology,Jinan University,Guangzhou,510632,China
3.Department of Materials Science and Engineering,Southern University of Science and Technology,Shenzhen,518055,China

Li，Huayang,Shen，Nan,Chen，Shi,et al. Recent Progress on Synthesis, Intrinsic Properties and Optoelectronic Applications of Perovskite Single Crystals[J]. Advanced Functional Materials,2023,33(24).

Li，Huayang,Shen，Nan,Chen，Shi,Guo，Fei,&Xu，Baomin.(2023).Recent Progress on Synthesis, Intrinsic Properties and Optoelectronic Applications of Perovskite Single Crystals.Advanced Functional Materials,33(24).

Li，Huayang,et al."Recent Progress on Synthesis, Intrinsic Properties and Optoelectronic Applications of Perovskite Single Crystals".Advanced Functional Materials 33.24(2023).