A strategy for regioselective B-H functionalization of o-carboranes via base metal catalysis

Zhang, Jie1,2; Xie, Zuowei1,2,3,4

2023-05-01

10.1039/d3qo00621b

ORGANIC CHEMISTRY FRONTIERS   影响因子和分区

2052-4129

Carboranes, a class of carbon-boron molecular clusters, have unique characteristics and are finding a variety of applications ranging from materials to medicine. In this connection, selective functionalization of o-carboranes has attracted enormous research interest, particularly in regio- and enantio-selective cage B-H derivatization among ten chemically similar BH vertices in o-carboranes. Over the years, precious transition metal-catalyzed cage B-H functionalization has made significant advances in the preparation of diversely functionalized o-carboranes. In contrast, research on B-H functionalization via a base metal catalysis strategy has just begun recently. This paper summarizes the recent developments in base metal-catalyzed regioselective B-H functionalization of carboranes.

SCI ; EI

英语

通讯

Research Grants Council of Hong Kong Special Administration Region["SRFS2021-4S05","14305420"]

Chemistry

Chemistry, Organic

WOS:000988687000001

ROYAL SOC CHEMISTRY

20232214170108

Catalysis ; Regioselectivity

Metallurgy and Metallography:531 ; Chemical Reactions:802.2

Web of Science

1.Chinese Univ Hong Kong, Dept Chem, Hong Kong, Peoples R China
2.Chinese Univ Hong Kong, State Key Lab Synthet Chem, Hong Kong, Peoples R China
3.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China
4.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China

Zhang, Jie,Xie, Zuowei. A strategy for regioselective B-H functionalization of o-carboranes via base metal catalysis[J]. ORGANIC CHEMISTRY FRONTIERS,2023,10(12):3074-3079.

Zhang, Jie,&Xie, Zuowei.(2023).A strategy for regioselective B-H functionalization of o-carboranes via base metal catalysis.ORGANIC CHEMISTRY FRONTIERS,10(12),3074-3079.

Zhang, Jie,et al."A strategy for regioselective B-H functionalization of o-carboranes via base metal catalysis".ORGANIC CHEMISTRY FRONTIERS 10.12(2023):3074-3079.