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题名

A comprehensive modelling study of all vanadium redox flow battery: Revealing the combined effects of electrode structure and surface property

作者
通讯作者Zhao,Tianshou
发表日期
2023-08-30
DOI
发表期刊
ISSN
2352-152X
EISSN
2352-152X
卷号66
摘要
To investigate the combined effects of electrode structural parameters and surface properties on the vanadium redox flow battery (VRFB) performance, a comprehensive model of VRFB is developed in this study. One feature of this study is that a practical range of working temperature is fully considered in the numerical simulations. Excellent VRFB performance was achieved by modified fibrous electrodes with 0.5 mm thickness and 0.9 porosity. The electrode with modified fibre of large diameter 20 μm shows improved battery performance with a low pressure drop. Without fibre modification, although VRFB with θ = 7° aligned fibre electrode reaches the highest limiting current density, it has an evidently high pressure drop. At 323.15 K, the VRFB with θ = 45° aligned fibre electrode showed 21 % higher limiting current density and 36 % lower pressure drop than VRFB with xy-plane isotropic electrode. Noteworthy, after the fibre surface modification, the sufficient specific surface area can be ensured, which leads to the insignificant effects of aligned electrode design. This model provides an insightful understanding of combined effects of electrode structure and surface property on the VRFBs performance at various temperatures.
关键词
相关链接[Scopus记录]
收录类别
SCI ; EI
语种
英语
学校署名
通讯
资助项目
Research Grants Council, University Grants Committee[T23–601/17-R];
WOS研究方向
Energy & Fuels
WOS类目
Energy & Fuels
WOS记录号
WOS:001007349200001
出版者
EI入藏号
20231713951945
EI主题词
Drops ; Fibers ; Flow batteries ; Numerical models ; Pressure drop ; Surface properties ; Vanadium
EI分类号
Vanadium and Alloys:543.6 ; Secondary Batteries:702.1.2 ; Mathematics:921 ; Physical Properties of Gases, Liquids and Solids:931.2 ; Materials Science:951
Scopus记录号
2-s2.0-85153104190
来源库
Scopus
引用统计
被引频次[WOS]:9
成果类型期刊论文
条目标识符http://sustech.caswiz.com/handle/2SGJ60CL/536412
专题工学院_机械与能源工程系
作者单位
1.Department of Building and Real Estate,Research Institute for Sustainable Urban Development (RISUD) & Research Institute for Smart Energy (RISE),The Hong Kong Polytechnic University,Kowloon,Hung Hom,Hong Kong
2.Department of Mechanical and Energy Engineering,Southern University of Science and Technology,Shenzhen,518055,China
通讯作者单位机械与能源工程系
推荐引用方式
GB/T 7714
He,Qijiao,Li,Zheng,Bello,Idris Temitope,et al. A comprehensive modelling study of all vanadium redox flow battery: Revealing the combined effects of electrode structure and surface property[J]. Journal of Energy Storage,2023,66.
APA
He,Qijiao.,Li,Zheng.,Bello,Idris Temitope.,Xu,Qidong.,Xia,Lingchao.,...&Ni,Meng.(2023).A comprehensive modelling study of all vanadium redox flow battery: Revealing the combined effects of electrode structure and surface property.Journal of Energy Storage,66.
MLA
He,Qijiao,et al."A comprehensive modelling study of all vanadium redox flow battery: Revealing the combined effects of electrode structure and surface property".Journal of Energy Storage 66(2023).
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