Chemical vapor deposition synthesis and Raman scattering investigation of quasi-one-dimensional ZrS3 nanoflakes

Chen，Yang1; Jin，Yuanyuan1; Yang，Junqiang4; Ren，Yizhang1; Duan，Zhuojun1; Liu，Xiao1; Sun，Jian4; Liu，Song1; Zhu，Xukun3; Duan，Xidong2

2023

10.1007/s12274-023-5695-x

Nano Research   影响因子和分区

1998-0124

1998-0000

Quasi-one-dimensional ZrS nanoflakes attract intense interest attributed to their superior electrical and optical anisotropy, stemming from the low symmetry in the crystal structure. However, the conventional chemical vapor transport method for synthesizing bulk ZrS is limited by morphology and size controllability. It is highly desirable to propose a facile way to precisely synthesize ZrS nanoflakes. In this work, the chemical vapor deposition method is proposed as a feasible way to synthesize ZrS nanoflakes. The effects of various substrates and temperatures on ZrS synthesis have been investigated. For the as-grown ZrS, good crystallinity is confirmed with X-ray diffraction and transmission electron microscopy. The structure and interlayer coupling are investigated with Raman scattering spectroscopy. The strong in-plane anisotropy and interlayer coupling of the ZrS nanoflakes are illustrated with angle-resolved Raman spectroscopy and temperature-dependent Raman characterization, respectively. This study demonstrates a feasible way for the synthesis of transition metal trisulfides, which may shed new light on the research of other two-dimensional anisotropic transition metal materials.[Figure not available: see fulltext.]

chemical vapor deposition method in-plane anisotropy interlayer coupling quasi-one-dimensional ZrS3 nanoflakes

SCI ; EI

英语

通讯

National Natural Science Foundation of China["22175060","21975067"] ; Natural Science Foundation of Hunan Province of China["2021JJ10014","2021JJ30092"]

Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics

Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied

WOS:000983053100008

TSINGHUA UNIV PRESS

20231914071117

Anisotropy ; Chemical vapor deposition ; Crystal symmetry ; Crystallinity ; High resolution transmission electron microscopy ; Raman scattering ; Raman spectroscopy ; Sulfur compounds ; Transition metals ; Transport properties

Metallurgy and Metallography:531 ; Light/Optics:741.1 ; Optical Devices and Systems:741.3 ; Chemical Reactions:802.2 ; Physical Properties of Gases, Liquids and Solids:931.2 ; Crystalline Solids:933.1 ; Crystal Lattice:933.1.1

2-s2.0-85158092701

Scopus

1.Institute of Chemical Biology and Nanomedicine (ICBN),College of Chemistry and Chemical Engineering,Hunan University,Changsha,410082,China
2.Hunan Key Laboratory of Two-Dimensional Materials and State Key Laboratory for Chemo/Biosensing and Chemometrics,College of Chemistry and Chemical Engineering,Hunan University,Changsha,410082,China
3.Department of Chemistry,Southern University of Science and Technology,Shenzhen,518055,China
4.School of Physics and Electronics,Central South University,Changsha,410083,China

Chen，Yang,Jin，Yuanyuan,Yang，Junqiang,et al. Chemical vapor deposition synthesis and Raman scattering investigation of quasi-one-dimensional ZrS3 nanoflakes[J]. Nano Research,2023,16(7):10567-10572.

Chen，Yang.,Jin，Yuanyuan.,Yang，Junqiang.,Ren，Yizhang.,Duan，Zhuojun.,...&Duan，Xidong.(2023).Chemical vapor deposition synthesis and Raman scattering investigation of quasi-one-dimensional ZrS3 nanoflakes.Nano Research,16(7),10567-10572.

Chen，Yang,et al."Chemical vapor deposition synthesis and Raman scattering investigation of quasi-one-dimensional ZrS3 nanoflakes".Nano Research 16.7(2023):10567-10572.