Deciphering dissolved organic matter by Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS): from bulk to fractions and individuals

Qi，Yulin1,2,3; Xie，Qiaorong1; Wang，Jun Jian4; He，Ding5; Bao，Hongyan6; Fu，Qing Long7; Su，Sihui1; Sheng，Ming1; Li，Si Liang1,2,3; Volmer，Dietrich A.8; Wu，Fengchang9; Jiang，Guibin10; Liu，Cong Qiang1,2,3; Fu，Pingqing1,2,3

2022-12-01

10.1007/s44246-022-00002-8

Carbon Research   影响因子和分区

2731-6696

Exploring the source, transformation pathways, and the fate of natural organic matter (NOM) is critical to understanding the regional/global carbon cycle and carbon budget. The dissolved fraction of NOM, i.e., dissolved organic matter (DOM), is a complex mixture resulting from the transformation of plant, animal and microbial matter and plays a crucial role in many biogeochemical processes at the land-ocean-atmosphere interfaces. The advance of Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS) makes the detailed characterization of DOM at the molecular level possible. On the other hand, elucidation of complex DOM sample also presents significant analytical challenges, and these challenges also act as a driving force for the instrumentation and methodology development on FT-ICR MS. This review article has been written to aid those working in biogeochemistry, environmental and atmospheric chemistry, and related areas which investigate elemental cycles and DOM transformations. First, the fundamental theory, historical perspective, and recent advances in the field have been introduced. The detailed molecular characterization of environmental and geological samples continues to present significant analytical challenges, and it also has become a driving force for the development of the instrumentation and experimental methods. These achievements in DOM analysis have had an impact upon the fields of environmental science, geochemistry, and analytical chemistry. Next, varieties of applications of FT-ICR MS have also been described, followed by our view of the future of this technique in earth science research. We believe that this review covers the essential pairing of FT-ICR MS and collectively offers environmental and geochemical scientists a substantial resource for their research. Graphical abstract: [Figure not available: see fulltext.].

Biogeochemistry Brown carbon DOM Environmental science FT-ICR MS Organic aerosol Soil organic matter

英语

其他

National Natural Science Foundation of China[42007290];National Natural Science Foundation of China[42130513];German-Israeli Foundation for Scientific Research and Development[DVG VO 1355/4-3];

2-s2.0-85135892981

Scopus

1.Institute of Surface-Earth System Science,School of Earth System Science,Tianjin University,Tianjin,China
2.Tianjin Key Laboratory of Earth Critical Zone Science and Sustainable Development in Bohai Rim,Tianjin University,Tianjin,China
3.Haihe Laboratory of Sustainable Chemical Transformations,Tianjin,China
4.State Environmental Protection Key Laboratory of Integrated Surface Water-Groundwater Pollution Control,School of Environmental Science and Engineering,Southern University of Science and Technology,Shenzhen,China
5.Department of Ocean Science and Hong Kong Branch of the Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou),The Hong Kong University of Science and Technology,Hong Kong
6.State Key Laboratory of Marine Environmental Science,College of Ocean and Earth Sciences,Xiamen University,Xiamen,China
7.School of Environmental Studies,China University of Geosciences,Wuhan,China
8.Department of Chemistry,Humboldt-Universität zu Berlin,Berlin,Germany
9.State Key Laboratory of Environmental Criteria and Risk Assessment,Chinese Research Academy of Environmental Sciences,Beijing,China
10.State Key Laboratory of Environmental Chemistry and Ecotoxicology,Research Center for Eco-Environmental Sciences,Chinese Academy of Sciences,Beijing,China

Qi，Yulin,Xie，Qiaorong,Wang，Jun Jian,et al. Deciphering dissolved organic matter by Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS): from bulk to fractions and individuals[J]. Carbon Research,2022,1(1).

Qi，Yulin.,Xie，Qiaorong.,Wang，Jun Jian.,He，Ding.,Bao，Hongyan.,...&Fu，Pingqing.(2022).Deciphering dissolved organic matter by Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS): from bulk to fractions and individuals.Carbon Research,1(1).

Qi，Yulin,et al."Deciphering dissolved organic matter by Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS): from bulk to fractions and individuals".Carbon Research 1.1(2022).