Low Ruthenium Content Confined on Boron Carbon Nitride as an Efficient and Stable Electrocatalyst for Acidic Oxygen Evolution Reaction

Bai，Xiaofang1; Zhang，Xiuping1; Sun，Yujiao1; Huang，Mingcheng1; Fan，Jiantao2,3; Xu，Shaoyi2,3; Li，Hui1,4,5

2023-09-18

10.1002/anie.202308704

Angewandte Chemie - International Edition   影响因子和分区

1433-7851

1521-3773

To date, only a few noble metal oxides exhibit the required efficiency and stability as oxygen evolution reaction (OER) catalysts under the acidic, high-voltage conditions that exist during proton exchange membrane water electrolysis (PEMWE). The high cost and scarcity of these catalysts hinder the large-scale application of PEMWE. Here, we report a novel OER electrocatalyst for OER comprised of uniformly dispersed Ru clusters confined on boron carbon nitride (BCN) support. Compared to RuO, our BCN-supported catalyst shows enhanced charge transfer. It displays a low overpotential of 164 mV at a current density of 10 mA cm, suggesting its excellent OER catalytic activity. This catalyst was able to operate continuously for over 12 h under acidic conditions, whereas RuO without any support fails in 1 h. Density functional theory (DFT) calculations confirm that the interaction between the N on BCN support and Ru clusters changes the adsorption capacity and reduces the OER energy barrier, which increases the electrocatalytic activity of Ru.

Boron Carbon Nitride Catalyst Oxygen Evolution Reaction Ruthenium Water Splitting

SCI ; EI

英语

NI论文

第一 ; 通讯

Key Technologies Research and Development Program[2021YFB4000200];Basic and Applied Basic Research Foundation of Guangdong Province[2022A1515011917];Shenzhen Fundamental Research Program[JCYJ20200109141216566];

Chemistry

Chemistry, Multidisciplinary

WOS:001044572800001

WILEY-V C H VERLAG GMBH

20233314541830

Catalyst activity ; Catalyst supports ; Charge transfer ; Electrocatalysts ; Nitrides ; Oxygen ; Precious metals ; Proton exchange membrane fuel cells (PEMFC) ; Ruthenium compounds

Precious Metals:547.1 ; Fuel Cells:702.2 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Inorganic Compounds:804.2 ; Probability Theory:922.1 ; Atomic and Molecular Physics:931.3 ; Quantum Theory; Quantum Mechanics:931.4

CHEMISTRY

2-s2.0-85167583032

Scopus

1.Department of Materials Science and Engineering,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China
2.Academy for Advanced Interdisciplinary Studies,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China
3.Guangdong Provincial Key Laboratory of Energy Materials for Electric Power,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China
4.Key University Laboratory of Highly Efficient Utilization of Solar Energy and Sustainable Development,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China
5.Shenzhen Key Laboratory of Hydrogen Energy,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China

Bai，Xiaofang,Zhang，Xiuping,Sun，Yujiao,et al. Low Ruthenium Content Confined on Boron Carbon Nitride as an Efficient and Stable Electrocatalyst for Acidic Oxygen Evolution Reaction[J]. Angewandte Chemie - International Edition,2023,62(38).

Bai，Xiaofang.,Zhang，Xiuping.,Sun，Yujiao.,Huang，Mingcheng.,Fan，Jiantao.,...&Li，Hui.(2023).Low Ruthenium Content Confined on Boron Carbon Nitride as an Efficient and Stable Electrocatalyst for Acidic Oxygen Evolution Reaction.Angewandte Chemie - International Edition,62(38).

Bai，Xiaofang,et al."Low Ruthenium Content Confined on Boron Carbon Nitride as an Efficient and Stable Electrocatalyst for Acidic Oxygen Evolution Reaction".Angewandte Chemie - International Edition 62.38(2023).