Performance Evaluation of a Scaled-Up Membraneless Organic-Based Hybrid Flow Battery

Yu，Feilin1; Zhao，Wenbo1; Leung，Puiki1; Mohamed，Mohd Rusllim2; Wei，Lei3; Shah，Akeel1; Liao，Qiang1

2023-07-01

10.3390/batteries9070336

Batteries   影响因子和分区

2313-0105

This article presents an evaluation of the performance of a membrane-less organic-based flow battery using low-cost active materials, zinc and benzoquinone, which was scaled up to 1600 cm, resulting in one of the largest of its type reported in the literature. The charge–discharge cycling of the battery was compared at different sizes and current densities, and its performance was evaluated under various mass transport and operating conditions. The results showed that the round-trip coulombic and voltage efficiencies were over 90% and 85%, respectively, for the laboratory-scale (1 cm electrode) cell, but these performances tended to deteriorate with the scaled-up (1600 cm electrode) cell due to inadequate mass transfer and sediment coverage of quinone, as well as the formation of a passivation film on the zinc anode. Despite this, the scaled-up batteries exhibited high coulombic and voltage efficiencies of up to 99% and 68.5%, respectively, at a current density of 10 mA cm. The capital cost of this system is also estimated to be several times lower than those of commercially available all-vanadium flow batteries and zinc bromide flow batteries for demand charge management applications.

capital cost analysis hybrid flow battery laboratory-scale cell performance evaluation scaled-up cell

SCI ; EI

英语

通讯

Fundamental Research Funds for the Central Universities[2021CDJQY-027];Innovative Research Group Project of the National Natural Science Foundation of China[52021004];National Natural Science Foundation of China[52206089];

Electrochemistry ; Energy & Fuels ; Materials Science

Electrochemistry ; Energy & Fuels ; Materials Science, Multidisciplinary

WOS:001037993100001

MDPI

20233114464491

Cost benefit analysis ; Electric discharges ; Electrodes ; Flow batteries ; Mass transfer ; Passivation ; Vanadium compounds ; Zinc compounds

Protection Methods:539.2.1 ; Mass Transfer:641.3 ; Electricity: Basic Concepts and Phenomena:701.1 ; Secondary Batteries:702.1.2 ; Cost and Value Engineering; Industrial Economics:911 ; Management:912.2 ; Production Engineering:913.1

2-s2.0-85166368006

Scopus

1.Key Laboratory of Low-Grade Energy Utilization Technologies and Systems,MOE,Chongqing University,Chongqing,400030,China
2.Faculty of Electrical and Electronics Engineering Technology,Universiti Malaysia Pahang,Pekan,26600,Malaysia
3.Department of Mechanical and Energy Engineering,SUSTech Energy Institute for Carbon Neutrality,Southern University of Science and Technology,Shenzhen,518055,China

Yu，Feilin,Zhao，Wenbo,Leung，Puiki,et al. Performance Evaluation of a Scaled-Up Membraneless Organic-Based Hybrid Flow Battery[J]. Batteries,2023,9(7).

Yu，Feilin.,Zhao，Wenbo.,Leung，Puiki.,Mohamed，Mohd Rusllim.,Wei，Lei.,...&Liao，Qiang.(2023).Performance Evaluation of a Scaled-Up Membraneless Organic-Based Hybrid Flow Battery.Batteries,9(7).

Yu，Feilin,et al."Performance Evaluation of a Scaled-Up Membraneless Organic-Based Hybrid Flow Battery".Batteries 9.7(2023).