南方科技大学知识苑(SUSTech KC): Stereodynamical control of the H + HD → H2 + D reaction through HD reagent alignment

题名	Stereodynamical control of the H + HD → H2 + D reaction through HD reagent alignment
作者	Wang，Yufeng 1; Huang，Jiayu 1; Wang，Wei 1,2; Du，Tianyu 1,2; Xie，Yurun1,3 ; Ma，Yuxin 1,2; Xiao，Chunlei 1,4; Zhang，Zhaojun 1; Zhang，Dong H.1,3,4 ; Yang，Xueming1,3,4
通讯作者	Xiao，Chunlei; Zhang，Zhaojun; Zhang，Dong H.; Yang，Xueming
发表日期	2023-01-13
DOI	10.1126/science.ade7471
发表期刊	Science 影响因子和分区
ISSN	0036-8075
EISSN	1095-9203
卷号	379 期号:6628页码:191-195
摘要	Prealigning nonpolar reacting molecules leads to large stereodynamical effects because of their weak steering interaction en route to the reaction barrier. However, experimental limitations in preparing aligned molecules efficiently have hindered the investigation of steric effects in bimolecular reactions involving hydrogen. Here, we report a high-resolution crossed-beam study of the reaction H + HD(v = 1, j = 2) → H(v′, j′) + D at collision energies of 0.50, 1.20, and 2.07 electron volts in which the vibrationally excited hydrogen deuteride (HD) molecules were prepared in two collision configurations, with their bond preferentially aligned parallel and perpendicular to the relative velocity of collision partners. Notable stereodynamical effects in differential cross sections were observed. Quantum dynamics calculations revealed that strong constructive interference in the perpendicular configuration plays an important role in the stereodynamical effects observed.
相关链接	[Scopus记录]
收录类别	SCI
语种	英语
重要成果	NI论文
学校署名	通讯
资助项目	Guangdong Science and Technology Department[2019JC01X091];Guangdong Science and Technology Department[2019ZT08L455];National Center of Competence in Research Quantum Science and Technology[2021ZD0303300];National Natural Science Foundation of China[22103084];National Natural Science Foundation of China[22173097];National Natural Science Foundation of China[22288201];National Natural Science Foundation of China[41827801];Chinese Academy of Sciences[GJJSTD20220001];Science and Technology Program of Jingdezhen City[ZDSYS20200421111001787];
WOS研究方向	Science & Technology - Other Topics
WOS类目	Multidisciplinary Sciences
WOS记录号	WOS:000933946800007
出版者	AMER ASSOC ADVANCEMENT SCIENCE
ESI学科分类	BIOLOGY & BIOCHEMISTRY;CLINICAL MEDICINE;MULTIDISCIPLINARY;PLANT & ANIMAL SCIENCE;ENVIRONMENT/ECOLOGY;SOCIAL SCIENCES, GENERAL;MICROBIOLOGY;ECONOMICS BUSINESS;IMMUNOLOGY;MATERIALS SCIENCE;MATHEMATICS;COMPUTER SCIENCE;SPACE SCIENCE;MOLECULAR BIOLOGY & GENETICS;CHEMISTRY;PSYCHIATRY/PSYCHOLOGY;NEUROSCIENCE & BEHAVIOR;PHYSICS;GEOSCIENCES;ENGINEERING
Scopus记录号	2-s2.0-85146194836
来源库	Scopus
引用统计	被引频次[WOS]：19
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/560022
专题	理学院_化学系
作者单位	1.State Key Laboratory of Molecular Reaction Dynamics,Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian,Liaoning,116023,China 2.School of Chemical Sciences,University of Chinese Academy of Sciences,Beijing,100049,China 3.Department of Chemistry,Shenzhen Key Laboratory of Energy Chemistry,Southern University of Science and Technology,Shenzhen,518055,China 4.Hefei National Laboratory,Hefei,230088,China
通讯作者单位	化学系
推荐引用方式 GB/T 7714	Wang，Yufeng,Huang，Jiayu,Wang，Wei,et al. Stereodynamical control of the H + HD → H2 + D reaction through HD reagent alignment[J]. Science,2023,379(6628):191-195.
APA	Wang，Yufeng.,Huang，Jiayu.,Wang，Wei.,Du，Tianyu.,Xie，Yurun.,...&Yang，Xueming.(2023).Stereodynamical control of the H + HD → H2 + D reaction through HD reagent alignment.Science,379(6628),191-195.
MLA	Wang，Yufeng,et al."Stereodynamical control of the H + HD → H2 + D reaction through HD reagent alignment".Science 379.6628(2023):191-195.