| 题名 | Anthryl-functionalized cyanide-bridged Fe/Co cubes |
| 作者 | |
| 通讯作者 | Zhang，Yuan Zhu |
| 发表日期 | 2023
|
| DOI | |
| 发表期刊 | |
| ISSN | 1477-9226
|
| EISSN | 1477-9234
|
| 卷号 | 52页码:12878-12884 |
| 摘要 | Two anthryl-functionalized cyanide-bridged [FeCo] cube complexes, [(pzTp)Fe(CN)Co(TpEtOAn)][OTf]·8MeCN·7EtO (1) and [NEt][(pzTp)Fe(CN)Co(TpEtOAn)][OTf]·5MeCN·2EtO (2) (pzTp = tetrapyrazolylborate, TpEtOAn = 2,2,2-tris-(pyrazol-1-yl)ethoxy(9-methyl-anthracene)), were synthesized and characterized. The crystallographic study revealed that the [FeCo] cubes are arranged into a linear supramolecular chain through significant anthryl-anthryl π-π stacking interactions in complex 1, whereas a zigzag supramolecular 1D assembly is observed in 2. The magnetic measurements showed that both compounds exhibited incomplete transitions from the paramagnetic {Fe(μ-CN)Co} state to the diamagnetic {Fe(μ-CN)Co} state at about 200 K. The luminescence measurement of 1 in solution revealed an enhancement of the emission upon dilution or addition of perfluoronaphthalene (PFN) molecules, which could be attributed to the suppression of the aggregation-caused quenching (ACQ) effect, suggesting possible aggregation of the cube units in the solution. |
| 相关链接 | [Scopus记录] |
| 收录类别 | |
| 语种 | 英语
|
| 学校署名 | 第一
|
| 资助项目 | This work was supported by the National Natural Science Foundation of China (no. 21901101 and 21671095) and the Stable Support Plan Program of the Shenzhen Natural Science Fund (no. 20200925151834005).["21671095","20200925151834005"]
; null[21901101]
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| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Inorganic & Nuclear
|
| WOS记录号 | WOS:001056950800001
|
| 出版者 | |
| EI入藏号 | 20233714728401
|
| EI主题词 | Cyanides
; Geometry
; Supramolecular chemistry
|
| EI分类号 | Physical Chemistry:801.4
; Chemical Reactions:802.2
; Inorganic Compounds:804.2
; Mathematics:921
|
| ESI学科分类 | CHEMISTRY
|
| Scopus记录号 | 2-s2.0-85170676773
|
| 来源库 | Scopus
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| 引用统计 |
被引频次[WOS]：1
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/560029 |
| 专题 | 理学院_化学系 |
| 作者单位 | Department of Chemistry,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China |
| 第一作者单位 | 化学系 |
| 第一作者的第一单位 | 化学系 |
| 推荐引用方式 GB/T 7714 |
Liu，Qi,Cheng，Yue,Liu，Shihao,et al. Anthryl-functionalized cyanide-bridged Fe/Co cubes[J]. Dalton Transactions,2023,52:12878-12884.
|
| APA |
Liu，Qi,Cheng，Yue,Liu，Shihao,Chen，Zi Yi,&Zhang，Yuan Zhu.(2023).Anthryl-functionalized cyanide-bridged Fe/Co cubes.Dalton Transactions,52,12878-12884.
|
| MLA |
Liu，Qi,et al."Anthryl-functionalized cyanide-bridged Fe/Co cubes".Dalton Transactions 52(2023):12878-12884.
|
| 条目包含的文件 | 条目无相关文件。 | |||||
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