Nonmetallic-Bonding Fe–Mn Diatomic Pairs Anchored on Hollow Carbonaceous Nanodisks for High-Performance Li–S Battery

Zhang，Tengfei1; Luo，Dengfeng2,3; Xiao，Hong1; Liang，Xiao1; Zhang，Fanchao1; Zhuang，Huifeng1; Xu，Mengyuan1; Dai，Wenjing1; Qi，Shuanhu1; Zheng，Lirong4; Gao，Qiuming1

2023

10.1002/smll.202306806

Small   影响因子和分区

1613-6810

1613-6829

The issues of polysulfide shuttling and lethargic sulfur redox reaction (SROR) kinetics are the toughest obstacles of lithium–sulfur (Li–S) battery. Herein, integrating the merits of increased density of metal sites and synergistic catalytic effect, a unique single-atom catalyst (SAC) with nonmetallic-bonding Fe–Mn diatomic pairs anchored on hollow nitrogen-doped carbonaceous nanodisk (denoted as FeMnDA@NC) is successfully constructed and well characterized by aberration-corrected high-angle annular dark-field scanning transmission electron microscopy, X-ray absorption spectroscopy, etc. Density functional theory calculation indicates that the Fe–Mn diatomic pairs can effectively inhibit the shuttle effect by enhancing the adsorption ability retarding the polysulfide migration and accelerate the SROR kinetics. As a result, the Li–S battery assembled with FeMnDA@NC modified separator possesses an excellent electrochemical performance with ultrahigh specific capacities of 1419 mAh g at 0.1 C and 885 mAh g at 3.0 C, respectively. An outstanding specific capacity of 1165 mAh g is achieved at 1.0 C and maintains at 731 mAh g after 700 cycles. Notably, the assembled Li–S battery with a high sulfur loading of 5.35 mg cm harvests a practical areal capacity of 5.70 mAh cm at 0.2 C. A new perspective is offered here to construct advanced SACs suitable for the Li–S battery.

dual-metal single-atom catalysts lithium–sulfur batteries nonmetallic bonding interaction separator modification synergistic effects

SCI ; EI

英语

其他

Chinese National Science Foundation["22075008","21571010","U0734002"] ; National Basic Research Programs of China["2014CB931800","2011CB935700"] ; Chinese Aeronautic Project[2013ZF51069] ; 111 Project[B14009]

Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics

Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter

WOS:001060856400001

WILEY-V C H VERLAG GMBH

20233714704917

Chemical bonds ; Density functional theory ; Doping (additives) ; High resolution transmission electron microscopy ; Lithium ; Lithium batteries ; Polysulfides ; Reaction kinetics ; Redox reactions ; Scanning electron microscopy ; Separators ; Sulfur ; X ray absorption spectroscopy

Lithium and Alloys:542.4 ; Alkali Metals:549.1 ; Primary Batteries:702.1.1 ; Optical Devices and Systems:741.3 ; Physical Chemistry:801.4 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Organic Polymers:815.1.1 ; Synthetic Rubber:818.2.1 ; Probability Theory:922.1 ; Atomic and Molecular Physics:931.3 ; Quantum Theory; Quantum Mechanics:931.4

2-s2.0-85170084433

Scopus

1.Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education,Beijing Advanced Innovation Center for Biomedical Engineering,School of Chemistry,Beihang University,Beijing,100191,China
2.Peng Cheng Laboratory,Shenzhen,518055,China
3.Department of Electrical and Electronic Engineering,Southern University of Science and Technology,Shenzhen,518055,China
4.Beijing Synchrotron Radiation Facility,Institute of High Energy Physics,Chinese Academy of Sciences,Beijing,100049,China

Zhang，Tengfei,Luo，Dengfeng,Xiao，Hong,等. Nonmetallic-Bonding Fe–Mn Diatomic Pairs Anchored on Hollow Carbonaceous Nanodisks for High-Performance Li–S Battery[J]. Small,2023,20(3).

Zhang，Tengfei.,Luo，Dengfeng.,Xiao，Hong.,Liang，Xiao.,Zhang，Fanchao.,...&Gao，Qiuming.(2023).Nonmetallic-Bonding Fe–Mn Diatomic Pairs Anchored on Hollow Carbonaceous Nanodisks for High-Performance Li–S Battery.Small,20(3).

Zhang，Tengfei,et al."Nonmetallic-Bonding Fe–Mn Diatomic Pairs Anchored on Hollow Carbonaceous Nanodisks for High-Performance Li–S Battery".Small 20.3(2023).