Selective Electrochemical Oxidation of p-Xylylene Glycol Coupled with the Hydrogen Evolution Reaction via a Continuous Flow Strategy

Zhang，Yuchi1; He，Xin4; Wang，Xiaofeng1; Zhao，Jiyang1; Cheng，Jiongjia1; Pan，Zhaorui1; Zheng，Bo1; Liu，Shaoxian1; Ma，Dui2,3; Wang，Hai Ying1

2023

10.1021/acssuschemeng.3c02018

ACS Sustainable Chemistry and Engineering   影响因子和分区

2168-0485

2168-0485

Catalytic oxidation of alcohols to their corresponding aldehydes and ketones plays a fundamental role in many industries, but conventional strategies suffer from high costs, harsh reaction conditions, and low energy efficiency. Here, we combine the p-xylylene glycol oxidation with the hydrogen evolution reaction via an I/I redox mediator in an electrochemical flow system where inexpensive graphite felt (GF) is utilized as electrodes. In comparison to traditional chemical oxidation, the electrochemical flow synthesis via the mediator I/I could offer an outstanding p-hydroxymethyl benzaldehyde selectivity of 96.5% and a Faradaic efficiency of 84.8%. Besides, we realize the gram-scale synthesis of p-hydroxymethyl benzaldehyde at the current density of 25 mA/cm with low energy consumption because of the prepared catalytically efficient GF-CuS and GF-Pt electrodes. We explore different substrates and observe the flexible adaptability of our proposed flow synthesis strategy, demonstrating its potential for industrial applications.

aldehyde synthesis electrochemistry flow synthesis green synthesis redox reaction

SCI ; EI

英语

其他

National Natural Science Foundation of China["21801127","22207055"] ; Shenzhen Science and Technology Program[RCBS20200714114818140] ; Guangdong Basic and Applied Basic Research Foundation[2022A1515011320] ; Fund of Nanchang Hangkong University[EA202201313]

Chemistry ; Science & Technology - Other Topics ; Engineering

Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical

WOS:001039797800001

AMER CHEMICAL SOC

20233614694026

Aldehydes ; Catalytic oxidation ; Electrochemical electrodes ; Electrochemical oxidation ; Electrooxidation ; Energy efficiency ; Energy utilization ; Glycols ; Graphite electrodes ; Hydrogen ; Ketones ; Methanol ; Polyols

Air Pollution Control:451.2 ; Energy Conservation:525.2 ; Energy Utilization:525.3 ; Electrochemistry:801.4.1 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Organic Compounds:804.1

2-s2.0-85169882217

Scopus

1.School of Environmental Science,Nanjing Xiaozhuang University,Nanjing,Jiangsu,211171,China
2.School of Materials Science and Engineering,Nanchang Hangkong University,Nanchang,330063,China
3.Research & Development Institute of Northwestern Polytechnical University in Shenzhen,Shenzhen,518000,China
4.Department of Chemistry,Academy for Advanced Interdisciplinary Studies,Shenzhen Engineering Research Center for Frontier Materials Synthesis at High Pressures,Southern University of Science and Technology (SUSTech),Shenzhen,518055,China

Zhang，Yuchi,He，Xin,Wang，Xiaofeng,et al. Selective Electrochemical Oxidation of p-Xylylene Glycol Coupled with the Hydrogen Evolution Reaction via a Continuous Flow Strategy[J]. ACS Sustainable Chemistry and Engineering,2023,11(32):11947-11954.

Zhang，Yuchi.,He，Xin.,Wang，Xiaofeng.,Zhao，Jiyang.,Cheng，Jiongjia.,...&Wang，Hai Ying.(2023).Selective Electrochemical Oxidation of p-Xylylene Glycol Coupled with the Hydrogen Evolution Reaction via a Continuous Flow Strategy.ACS Sustainable Chemistry and Engineering,11(32),11947-11954.

Zhang，Yuchi,et al."Selective Electrochemical Oxidation of p-Xylylene Glycol Coupled with the Hydrogen Evolution Reaction via a Continuous Flow Strategy".ACS Sustainable Chemistry and Engineering 11.32(2023):11947-11954.