Amine-Functionalized Carbon Dots as PEDOT:PSS Dopants for Organic Solar Cells

Li，Xin1; Wang，Wei1,2; Zhong，Wentao1; Tang，Yirong1; Wang，Xinyuan1; Li，Huan1; Yang，Tingbin3; Liang，Yongye1,4

2023

10.1002/admi.202300502

Advanced Materials Interfaces   影响因子和分区

2196-7350

2196-7350

The hole transport layer (HTL) is an important component in organic solar cells (OSCs). As a commonly used HTL, poly(3,4-ethylenedioxythiophene):poly(styrene-sulfonate) (PEDOT:PSS) in OSCs generally exhibits relatively low conductivity, hindering device performance improvement. Herein, amine-functionalized carbon dots (CDs-N) are introduced as dopants of PEDOT:PSS, which can effectively enhance the HTL conductivity while maintaining a similar work function. The PEDOT:PSS+CDs-N devices exhibit higher power conversion efficiencies due to the improved charge extraction ability. It is found that the larger conjugated backbones of CDs-N and the amine functional groups interacting with PSS are keys for such optimization. This work illustrates the potential of CDs for the applications on interface layers in OSCs.

amine functionalized carbon dots conductivity hole transport layers organic solar cells PEDOT:PSS

SCI ; EI

英语

第一 ; 通讯

Shenzhen Fundamental Research Funding (Key Program)[JCYJ20200109141405950] ; Guangdong-Hong Kong-Macao Joint Laboratory for Photonic-Thermal-Electrical Energy Materials and Devices[2019B121205001]

Chemistry ; Materials Science

Chemistry, Multidisciplinary ; Materials Science, Multidisciplinary

WOS:001061369300001

WILEY

20233614677066

Carbon ; Conducting polymers ; Conversion efficiency ; Hole mobility ; Styrene

Energy Conversion Issues:525.5 ; Solar Cells:702.3 ; Conducting Materials:708.2 ; Semiconducting Materials:712.1 ; Chemical Products Generally:804 ; Organic Compounds:804.1 ; Polymeric Materials:815.1

2-s2.0-85169587451

Scopus

1.Shenzhen Key Laboratory of Printed Electronics,Department of Materials Science and Engineering,Southern University of Science and Technology,Shenzhen,518055,China
2.Experiment and Practice Innovation Education Center,Beijing Normal University,Zhuhai,519087,China
3.Core Research Facilities,Southern University of Science and Technology,Shenzhen,518055,China
4.Guangdong-Hong Kong-Macao Joint Laboratory for Photonic-Thermal-Electrical Energy Materials and Devices,Southern University of Science and Technology,Shenzhen,518055,China

Li，Xin,Wang，Wei,Zhong，Wentao,et al. Amine-Functionalized Carbon Dots as PEDOT:PSS Dopants for Organic Solar Cells[J]. Advanced Materials Interfaces,2023,10(35).

Li，Xin.,Wang，Wei.,Zhong，Wentao.,Tang，Yirong.,Wang，Xinyuan.,...&Liang，Yongye.(2023).Amine-Functionalized Carbon Dots as PEDOT:PSS Dopants for Organic Solar Cells.Advanced Materials Interfaces,10(35).

Li，Xin,et al."Amine-Functionalized Carbon Dots as PEDOT:PSS Dopants for Organic Solar Cells".Advanced Materials Interfaces 10.35(2023).