Ultrafast Synthesis of Nasicon Solid Electrolytes for Sodium-Metal Batteries

Zuo，Daxian1; Yang，Lin1; Zou，Zheyi2; Li，Shen2; Feng，Yitian1; Harris，Stephen J.3; Shi，Siqi4; Wan，Jiayu5

2023

10.1002/aenm.202301540

Advanced Energy Materials   影响因子和分区

1614-6832

1614-6840

NASICON-structured solid-state electrolytes (SSEs) are highly promising materials for sodium solid-state metal batteries (NaSMBs). However, the current synthesis methods are often labor-intensive and inefficient, consuming a significant amount of energy and time. Here, an ultrafast high-temperature synthesis (UHS) technique is successfully demonstrated to directly synthesize NASICON-type SSEs from mixed precursor powders, reducing the synthesis time from hours to merely seconds. The intermediate with a NaPO structure plays a critical role in the rapid synthesis of NASICON-type SSEs, ultimately leading to the formation of the final NASICON phase. Moreover, the UHS-synthesizes NASICON-type NaZrLuSiPO (NZLSP) exhibits high room temperature ionic conductivity of 7.7 × 10 S cm, approximately three times that of the undoped NaZrSiPO (NZSP). The Na|NZLSP|Na symmetric cell can sustain highly stable cycling for over 4800 h. This study provides a novel insight and validation in the precise and targeted synthesis of complex oxide solid-state electrolytes.

ionic conductivity NASICON structure rapid synthesis sodium-metal batteries solid-state electrolytes

SCI ; EI

英语

第一

National Natural Science Foundation of China["52272215","52102313"]

Chemistry ; Energy & Fuels ; Materials Science ; Physics

Chemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter

WOS:001050455100001

WILEY-V C H VERLAG GMBH

20233414594631

Ionic conduction in solids ; Lutetium compounds ; Silicon ; Silicon compounds ; Sodium ; Sodium compounds ; Solid electrolytes ; Solid oxide fuel cells (SOFC) ; Solid-State Batteries ; Yttrium compounds ; Zirconium compounds

Alkali Metals:549.1 ; Nonferrous Metals and Alloys excluding Alkali and Alkaline Earth Metals:549.3 ; Electricity: Basic Concepts and Phenomena:701.1 ; Secondary Batteries:702.1.2 ; Fuel Cells:702.2 ; Chemical Agents and Basic Industrial Chemicals:803

2-s2.0-85168276703

Scopus

1.Department of Mechanical and Energy Engineering,Southern University of Science and Technology,Shenzhen,518055,China
2.School of Materials Science and Engineering,Xiangtan University,Xiangtan,Hunan,411105,China
3.Energy Storage and Distributed Resources Division,Lawrence Berkeley National Laboratory,Berkeley,94720,United States
4.School of Materials Science and Engineering,Shanghai University,Shanghai,200444,China
5.Future Battery Research Center,Global Institute of Future Technology,Shanghai Jiaotong University,Shanghai,200240,China

Zuo，Daxian,Yang，Lin,Zou，Zheyi,et al. Ultrafast Synthesis of Nasicon Solid Electrolytes for Sodium-Metal Batteries[J]. Advanced Energy Materials,2023,13.

Zuo，Daxian.,Yang，Lin.,Zou，Zheyi.,Li，Shen.,Feng，Yitian.,...&Wan，Jiayu.(2023).Ultrafast Synthesis of Nasicon Solid Electrolytes for Sodium-Metal Batteries.Advanced Energy Materials,13.

Zuo，Daxian,et al."Ultrafast Synthesis of Nasicon Solid Electrolytes for Sodium-Metal Batteries".Advanced Energy Materials 13(2023).