南方科技大学知识苑(SUSTech KC): Assessing Dual Rh/Ru Cascade Catalysts in One-Pot Homogeneous Synthesis of Ethanol from Syngas and Methanol

题名	Assessing Dual Rh/Ru Cascade Catalysts in One-Pot Homogeneous Synthesis of Ethanol from Syngas and Methanol
作者	Zhang, Ji-Shu1,2 ; Jiang, Ya-Fei1 ; Guan, Fanfu1,2 ; Zhang, Shaoke1,2 ; Xu, Cong-Qiao1 ; Bai, Shao-Tao1,3 ; Wen, Jialin1,3 ; Li, Jun1,4 ; Zhang, Xumu1,2
通讯作者	Li, Jun; Zhang, Xumu
发表日期	2023-06-01
DOI	10.31635/ccschem.022.202202048
发表期刊	CCS CHEMISTRY 影响因子和分区
EISSN	2096-5745
卷号	5 期号:7
摘要	["The direct conversion of cheap syngas into value-added ethanol at an industrial scale is in high demand. Herein we disclose a one-pot homogeneous homologation of methanol to ethanol with syngas via a rhodium/ruthenium bimetallic catalytic approach. By introducing a catalytic amount of methyl iodide, methanol can be converted to ethanol with high selectivity (>91% ethanol). A syngas ratio of H-2/CO = 4:1 was found to be optimal. Among various phosphine ligands tested, Rh-dppp catalyst gave the highest aldehyde pathway selectivity, thus providing an effective route for the synthesis of ethanol upon coupling with a Ru hydrogenation catalyst. The bite angle of the bisphosphine ligands dramatically influences the selectivity of the dual Rh/Ru metallic cascade catalysts. In line with the experimental findings, theoretical calculations predicted a rational trend of the selectivity of different bisphosphine ligands via varying bite angle properties.","[GRAPHICS]","."]
关键词	methanol homologation ethanol rhodium ruthenium syngas
相关链接	[来源记录]
收录类别	ESCI
语种	英语
学校署名	第一 ; 通讯
资助项目	National Natural Science Foundation of China["22033005","22103035"] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; Science, Technology, and Innovation Commission of Shenzhen[20200925161222002]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:001081157300008
出版者	CHINESE CHEMICAL SOC
来源库	Web of Science
引用统计	被引频次[WOS]：2
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/582856
专题	理学院_化学系前沿与交叉科学研究院
作者单位	1.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol, Acad Adv Interdisciplinary Studies, Shenzhen 518055, Peoples R China 4.Tsinghua Univ, Dept Chem, Key Lab Organ Optoelect & Mol Engn, Minist Educ, Beijing 100084, Peoples R China
第一作者单位	化学系; 南方科技大学
通讯作者单位	化学系; 南方科技大学
第一作者的第一单位	化学系
推荐引用方式 GB/T 7714	Zhang, Ji-Shu,Jiang, Ya-Fei,Guan, Fanfu,et al. Assessing Dual Rh/Ru Cascade Catalysts in One-Pot Homogeneous Synthesis of Ethanol from Syngas and Methanol[J]. CCS CHEMISTRY,2023,5(7).
APA	Zhang, Ji-Shu.,Jiang, Ya-Fei.,Guan, Fanfu.,Zhang, Shaoke.,Xu, Cong-Qiao.,...&Zhang, Xumu.(2023).Assessing Dual Rh/Ru Cascade Catalysts in One-Pot Homogeneous Synthesis of Ethanol from Syngas and Methanol.CCS CHEMISTRY,5(7).
MLA	Zhang, Ji-Shu,et al."Assessing Dual Rh/Ru Cascade Catalysts in One-Pot Homogeneous Synthesis of Ethanol from Syngas and Methanol".CCS CHEMISTRY 5.7(2023).