南方科技大学知识苑(SUSTech KC): Facile and Stable CuInO<sub>2</sub> Nanoparticles for Efficient Electrochemical CO<sub>2</sub> Reduction

题名	Facile and Stable CuInO₂ Nanoparticles for Efficient Electrochemical CO₂ Reduction
作者	Yin, Lihong 1,2 ; Li, Zhiqiang 2 ; Feng, Jinxian 1; Zhou, Pengfei 1; Qiao, Lulu 1; Liu, Di 1; Yi, Zhibin2 ; Ip, Weng Fai 3; Luo, Guangfu2,4 ; Pan, Hui 1,3
通讯作者	Ip, Weng Fai; Luo, Guangfu; Pan, Hui
发表日期	2023-10-02
DOI	10.1021/acsami.3c11342
发表期刊	ACS APPLIED MATERIALS & INTERFACES 影响因子和分区
ISSN	1944-8244
EISSN	1944-8252
卷号	15 期号:40页码:47135-47144
摘要	Searching for electrocatalysts for the electrochemical CO(2 )reduction reaction (e-CO2RR) with high selectivity and stability remains a significant challenge. In this study, we design a Cu-CuInO2 composite with stable states of Cu-0/Cu+ by electrochemically depositing indium onto CuCl-decorated Cu foil. The catalyst displays superior selectivity toward the CO product, with a maximal Faraday efficiency of 89% at -0.9 V vs the reversible hydrogen electrode, and maintains impressive stability up to 27 h with a retention rate of >76% in Faraday efficiency. Our systematical characterizations reveal that the catalyst's high performance is attributed to CuInO2 nanoparticles. First-principles calculations further confirm that CuInO2(012) is more conducive to CO generation than Cu(111) under applied potential and presents a higher energy barrier than Cu(111) for the hydrogen evolution reaction. These theoretical predictions are consistent with our experimental observations, suggesting that CuInO2 nanoparticles offer a facile catalyst with a high selectivity and stability for e-CO2RR.
关键词	electrochemical CO2 reduction reaction electrocatalysts CuInO2 nanoparticles first-principles calculations hydrogen evolution reaction
相关链接	[来源记录]
收录类别	SCI ; EI
语种	英语
学校署名	通讯
资助项目	Research amp; Development Office at University of Macau[SGDX20210823103803017] ; Shenzhen-Hong Kong-Macao Science and Technology Research Programme[2019B030301001] ; Shenzhen, Guangdong Provincial Key Laboratory of Computational Science and Material Design[2017ZT07C062] ; Introduced Innovative R Team of Guangdong[JCYJ20200109141412308] ; Shenzhen Science and Technology Innovation Commission[52273226]
WOS研究方向	Science & Technology - Other Topics ; Materials Science
WOS类目	Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS记录号	WOS:001076277300001
出版者	AMER CHEMICAL SOC
EI入藏号	20234615049043
EI主题词	Carbon dioxide ; Catalyst selectivity ; Copper compounds ; Electrocatalysts ; Indium compounds ; Reduction
EI分类号	Nanotechnology:761 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Inorganic Compounds:804.2 ; Solid State Physics:933
来源库	Web of Science
引用统计	被引频次[WOS]：7
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/582996
专题	工学院_材料科学与工程系
作者单位	1.Univ Macau, Inst Appl Phys & Mat Engn, Taipa 999078, Peoples R China 2.Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen 518055, Peoples R China 3.Univ Macau, Fac Sci & Technol, Dept Phys & Chem, Macau 999078, Peoples R China 4.Southern Univ Sci & Technol, Guangdong Prov Key Lab Computat Sci & Mat Design, Shenzhen 518055, Peoples R China
第一作者单位	材料科学与工程系
通讯作者单位	材料科学与工程系; 南方科技大学
推荐引用方式 GB/T 7714	Yin, Lihong,Li, Zhiqiang,Feng, Jinxian,et al. Facile and Stable CuInO₂ Nanoparticles for Efficient Electrochemical CO₂ Reduction[J]. ACS APPLIED MATERIALS & INTERFACES,2023,15(40):47135-47144.
APA	Yin, Lihong.,Li, Zhiqiang.,Feng, Jinxian.,Zhou, Pengfei.,Qiao, Lulu.,...&Pan, Hui.(2023).Facile and Stable CuInO₂ Nanoparticles for Efficient Electrochemical CO₂ Reduction.ACS APPLIED MATERIALS & INTERFACES,15(40),47135-47144.
MLA	Yin, Lihong,et al."Facile and Stable CuInO₂ Nanoparticles for Efficient Electrochemical CO₂ Reduction".ACS APPLIED MATERIALS & INTERFACES 15.40(2023):47135-47144.