Topological insulator as an efficient catalyst for oxidative carbonylation of amines

Li, Jiang1; Wu, Jiazhen1,2; Park, Sang-won1,3; Sasase, Masato1; Ye, Tian-Nan1,4; Lu, Yangfan1,5; Miyazaki, Masayoshi1; Yokoyama, Toshiharu1; Tada, Tomofumi1; Kitano, Masaaki1; Hosono, Hideo1,6

2023-09-22

10.1126/sciadv.adh9104

SCIENCE ADVANCES   影响因子和分区

2375-2548

Topological materials have received much attention because of their robust topological surface states, which can be potentially applied in electronics and catalysis. Here, we show that the topological insulator bismuth selenide functions as an efficient catalyst for the oxidative carbonylation of amines with carbon monoxide and dioxygen to synthesize urea derivatives. For example, the carbonylation of butylamine can be completed over bismuth selenide nanoparticle catalyst in 4 hours at 20? with a yield of 99%, whereas most noble metal-based catalysts do not function at such a low temperature. Density functional theory calculations further reveal that the topological surface states facilitate the activation of dioxygen through a triplet-to-singlet spin-conversion reaction, in which active oxygen species are formed with a barrier of 0.4 electron volts for the subsequent reactions with amine and carbon monoxide.

SCI ; EI

英语

NI论文

其他

Research Center of the Ministry of Education, Culture, Sports, Science and Technology (MEXT;Japan )[JPMXP0112101001] ; ST MIRAI PROGRAM[JPMJMI21E9] ; FOREST Program from JST[JPMJFR203A] ; National Natural Science Foundation of China[52173284] ; Shenzhen fundamental research funding[JCYJ20210324115809026] ; Guangdong Provincial Department of Education Innovation Team Program[2021KCXTD012]

Science & Technology - Other Topics

Multidisciplinary Sciences

WOS:001071484100002

AMER ASSOC ADVANCEMENT SCIENCE

20234515042757

Bismuth compounds ; Carbon monoxide ; Carbonylation ; Catalysts ; Density functional theory ; Electric insulators ; Metal nanoparticles ; Precious metals ; Surface states ; Temperature ; Topology ; Urea

Precious Metals:547.1 ; Thermodynamics:641.1 ; Nanotechnology:761 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804 ; Organic Compounds:804.1 ; Inorganic Compounds:804.2 ; Combinatorial Mathematics, Includes Graph Theory, Set Theory:921.4 ; Probability Theory:922.1 ; Classical Physics; Quantum Theory; Relativity:931 ; Atomic and Molecular Physics:931.3 ; Quantum Theory; Quantum Mechanics:931.4 ; High Energy Physics; Nuclear Physics; Plasma Physics:932

Web of Science

1.Tokyo Inst Technol, MDX Res Ctr Element Strategy, Int Res Frontiers Initiat, 4259 Nagatsuta,Midori Ku, Yokohama 2268503, Japan
2.Southern Univ Sci & Technol, Dept Mat Sci & Engn, Shenzhen 518055, Guangdong, Peoples R China
3.Univ Suwon, Dept Chem & Mat Engn, 17 Wauan Gil, Hwaseong 18323, Gyeonggi, South Korea
4.Shanghai Jiao Tong Univ, Frontiers Sci Ctr Transformat Mol, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China
5.Chongqing Univ, Coll Mat Sci & Engn, Natl Engn Res Ctr Magnesium Alloys, Chongqing 400030, Peoples R China
6.Natl Inst Mat Sci NIMS, Int Ctr Mat Nanoarchitecton WPI MANA, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan

Li, Jiang,Wu, Jiazhen,Park, Sang-won,et al. Topological insulator as an efficient catalyst for oxidative carbonylation of amines[J]. SCIENCE ADVANCES,2023,9(38).

Li, Jiang.,Wu, Jiazhen.,Park, Sang-won.,Sasase, Masato.,Ye, Tian-Nan.,...&Hosono, Hideo.(2023).Topological insulator as an efficient catalyst for oxidative carbonylation of amines.SCIENCE ADVANCES,9(38).

Li, Jiang,et al."Topological insulator as an efficient catalyst for oxidative carbonylation of amines".SCIENCE ADVANCES 9.38(2023).