南方科技大学知识苑(SUSTech KC): Alkylation and Arylation at Boron in NHC-Stabilized Phosphaborenes

题名	Alkylation and Arylation at Boron in NHC-Stabilized Phosphaborenes
作者	Li, Jiancheng1,2 ; Mei, Yanbo1,2,3,4 ; Wang, Xin-Feng1,2 ; Liu, Liu Leo1,2
通讯作者	Liu, Liu Leo
发表日期	2023-11-01
DOI	10.1002/asia.202300794
发表期刊	CHEMISTRY-AN ASIAN JOURNAL 影响因子和分区
ISSN	1861-4728
EISSN	1861-471X
卷号	19 期号:1
摘要	["Phosphaborenes, featuring a phosphorus-boron multiple bond, remain a relatively untapped area in chemical research due to the limited synthetic methods. Introducing leaving groups as substituents to the phosphorus or boron can pave the way for enhanced functionalization and modification. In this study, we present the synthesis of phosphaborenes featuring an N-heterocyclic boryl group on phosphorus and halogen substituent on boron, with stabilization provided by an N-heterocyclic carbene. Straightforward alkylation/arylation of these phosphaborenes is achieved by substituting the halogen with benzyl and aryl groups at the boron terminus. Our approach offers an efficient route to produce a diverse array of phosphaborene structures.","The synthesis of phosphaborenes stabilized by N-heterocyclic carbene (NHC) and featuring halogen substituents on boron has been documented. These compounds demonstrate the capability for direct alkylation/arylation, allowing for structural variations at the boron site.+image"]
关键词	Phosphaborenes Main Group Elements Alkylation Arylation N-Heterocyclic Carbenes
相关链接	[来源记录]
收录类别	SCI ; EI
语种	英语
学校署名	第一 ; 通讯
资助项目	Shenzhen Science and Technology Innovation Program[JCYJ20220530114806015] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; null[22301122] ; null[22201122] ; null[22271132] ; null[22101114]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:001108767900001
出版者	WILEY-V C H VERLAG GMBH
Scopus记录号	2-s2.0-85178140452
来源库	Web of Science
引用统计	被引频次[WOS]：1
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/629105
专题	理学院_化学系
作者单位	1.Southern Univ Sci & Technol, Coll Sci, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Peoples R China 2.Southern Univ Sci & Technol, Coll Sci, Res Ctr Chem Biol & Om Anal, Shenzhen 518055, Peoples R China 3.Great Bay Univ, Dept Chem, Dongguan 523000, Peoples R China 4.Great Bay Univ, Dongguan Key Lab Data Sci & Intelligent Med, Dongguan 523000, Peoples R China
第一作者单位	化学系; 南方科技大学
通讯作者单位	化学系; 南方科技大学
第一作者的第一单位	化学系
推荐引用方式 GB/T 7714	Li, Jiancheng,Mei, Yanbo,Wang, Xin-Feng,et al. Alkylation and Arylation at Boron in NHC-Stabilized Phosphaborenes[J]. CHEMISTRY-AN ASIAN JOURNAL,2023,19(1).
APA	Li, Jiancheng,Mei, Yanbo,Wang, Xin-Feng,&Liu, Liu Leo.(2023).Alkylation and Arylation at Boron in NHC-Stabilized Phosphaborenes.CHEMISTRY-AN ASIAN JOURNAL,19(1).
MLA	Li, Jiancheng,et al."Alkylation and Arylation at Boron in NHC-Stabilized Phosphaborenes".CHEMISTRY-AN ASIAN JOURNAL 19.1(2023).