Comprehensive Understandings of Hydrogen Bond Chemistry in Aqueous Batteries

Li, Ming1,2; Wang, Xuanpeng3,4; Meng, Jiashen1; Zuo, Chunli1; Wu, Buke5; Li, Cong1; Sun, Wei2; Mai, Liqiang1,4

2023-11-01

10.1002/adma.202308628

ADVANCED MATERIALS   影响因子和分区

0935-9648

1521-4095

["Aqueous batteries are emerging as highly promising contenders for large-scale grid energy storage because of uncomplicated assembly, exceptional safety, and cost-effectiveness. The unique aqueous electrolyte with a rich hydrogen bond (HB) environment inevitably has a significant impact on the electrode materials and electrochemical processes. While numerous reviews have focused on the materials design and assembly of aqueous batteries, the utilization of HB chemistry is overlooked. Herein, instead of merely compiling recent advancements, this review presents a comprehensive summary and analysis of the profound implication exerted by HB on all components of the aqueous batteries. Intricate links between the novel HB chemistry and various aqueous batteries are ingeniously constructed within the critical aspects, such as self-discharge, structural stability of electrode materials, pulverization, solvation structures, charge carrier diffusion, corrosion reactions, pH sensitivity, water splitting, polysulfides shuttle, and H2S evolution. By adopting a vantage point that encompasses material design, binder and separator functionalization, electrolyte regulation, and HB optimization, a critical examination of the key factors that impede electrochemical performance in diverse aqueous batteries is conducted. Finally, insights are rendered properly based on HB chemistry, with the aim of propelling the advancement of state-of-the-art aqueous batteries.","A comprehensive review is provided on the application and key factors of hydrogen bond chemistry in various aqueous batteries, encompassing electrode materials, electrolytes, separators, and binders. Accurate insights are presented to utilize hydrogen bond chemistry in order to address a range of key factors that hinder electrochemical performance, aiming to drive the progress of state-of-the-art aqueous batteries.image"]

anode protection aqueous batteries binders and separators functionalization electrolyte optimization hydrogen bond

SCI ; EI

英语

其他

National Key Research and Development Program of China[2020YFA0715000] ; National Natural Science Foundation of China["52127816","51832004","52373306"] ; Natural Science Foundation of Hubei Province["2023AFA053","2019CFA001"] ; Natural Science Foundation of Sichuan Province[2023NSFSC0116] ; null[2021CXLH0007]

Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics

Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter

WOS:001108955500001

WILEY-V C H VERLAG GMBH

MATERIALS SCIENCE

2-s2.0-85178104939

Web of Science

1.Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Peoples R China
2.Univ Elect Sci & Technol China, Sch Mat & Energy, Chengdu 611731, Peoples R China
3.Wuhan Univ Technol, Sch Sci, Dept Phys Sci & Technol, Wuhan 430070, Peoples R China
4.Wuhan Univ Technol, Hubei Longzhong Lab, Xiangyang 441000, Hubei, Peoples R China
5.Southern Univ Sci & Technol, Dept Mech & Energy Engn, Shenzhen 518055, Peoples R China

Li, Ming,Wang, Xuanpeng,Meng, Jiashen,et al. Comprehensive Understandings of Hydrogen Bond Chemistry in Aqueous Batteries[J]. ADVANCED MATERIALS,2023,36(3).

Li, Ming.,Wang, Xuanpeng.,Meng, Jiashen.,Zuo, Chunli.,Wu, Buke.,...&Mai, Liqiang.(2023).Comprehensive Understandings of Hydrogen Bond Chemistry in Aqueous Batteries.ADVANCED MATERIALS,36(3).

Li, Ming,et al."Comprehensive Understandings of Hydrogen Bond Chemistry in Aqueous Batteries".ADVANCED MATERIALS 36.3(2023).