南方科技大学知识苑(SUSTech KC): Cyanide-Bridged Rope-like Chains Based on Trigonal-Bipyramidal [Fe<sub>2</sub>Cu<sub>3</sub>] Subunits

题名	Cyanide-Bridged Rope-like Chains Based on Trigonal-Bipyramidal [Fe₂Cu₃] Subunits
作者	Yang, Jiong1 ; You, Mao-Lin1 ; Liu, Shihao 1 ; Deng, Yi-Fei1 ; Chang, Xiao-Yong1 ; Holmes, Stephen M.2,3; Zhang, Yuan-Zhu1
通讯作者	Deng, Yi-Fei; Holmes, Stephen M.; Zhang, Yuan-Zhu
发表日期	2023-10-06
DOI	10.1021/acs.inorgchem.3c02986
发表期刊	INORGANIC CHEMISTRY 影响因子和分区
ISSN	0020-1669
EISSN	1520-510X
卷号	62 期号:42页码:17530-17536
摘要	Extending a selected cyanometalate block into a higher dimensional framework continues to present intriguing challenges in the fields of chemistry and material science. Here, we prepared two rope-like chain compounds of {[(Tp(Me))Fe(CN)(3)](2)Cu2X2(L)}sol (1, X = Cl, L = (MeCN)(0.5)(H2O/MeOH)(0.5), sol = 2MeCN1.5H(2)O; 2, X = Br, L = MeOH, sol = 2MeCN0.75H(2)O; Tp(Me) = tris(3, 4, 5-trimethylpyrazole)borate) in which the cyanide-bridged trigonal-bipyramidal [Fe2Cu3] subunits were linked with the adjacent ones via two vertex Cu(II) centers, providing a new cyanometallate chain archetype. Direct current magnetic study revealed the presence of ferromagnetic couplings between Fe(III) and Cu(II) ions and uniaxial anisotropy due to a favorable alignment of the anisotropic tricyanoiron(III) units. Moreover, compound 1 exhibits single-chain magnet behavior with an appreciable energy barrier of 72 K, while 2 behaves as a metamagnet, likely caused by the subtle changes in the interchain interactions.
相关链接	[来源记录]
收录类别	SCI ; EI
语种	英语
重要成果	NI论文
学校署名	第一 ; 通讯
资助项目	Stable Support Plan Program of Shenzhen Natural Science Fund[20200925151834005] ; National Natural Science Foundation of China["21901108","22173043"] ; Guangdong Basic and Applied Basic Research Foundation[2022A1515011818] ; National Science Foundation["CHE-1214063","CHE-1800578"]
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
WOS记录号	WOS:001090485200001
出版者	AMER CHEMICAL SOC
EI入藏号	20234515042615
EI主题词	Anisotropy ; Copper compounds ; Cyanides ; Iron compounds ; Rope
EI分类号	Chemical Products Generally:804 ; Inorganic Compounds:804.2 ; Physical Properties of Gases, Liquids and Solids:931.2
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：2
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/629254
专题	理学院_化学系
作者单位	1.Southern Univ Sci & Technol SUSTech, Dept Chem, Shenzhen 518055, Peoples R China 2.Univ Missouri St Louis, Dept Chem & Biochem, St Louis, MO 63121 USA 3.Univ Missouri St Louis, Ctr Nanosci, St Louis, MO 63121 USA
第一作者单位	化学系
通讯作者单位	化学系
第一作者的第一单位	化学系
推荐引用方式 GB/T 7714	Yang, Jiong,You, Mao-Lin,Liu, Shihao,et al. Cyanide-Bridged Rope-like Chains Based on Trigonal-Bipyramidal [Fe₂Cu₃] Subunits[J]. INORGANIC CHEMISTRY,2023,62(42):17530-17536.
APA	Yang, Jiong.,You, Mao-Lin.,Liu, Shihao.,Deng, Yi-Fei.,Chang, Xiao-Yong.,...&Zhang, Yuan-Zhu.(2023).Cyanide-Bridged Rope-like Chains Based on Trigonal-Bipyramidal [Fe₂Cu₃] Subunits.INORGANIC CHEMISTRY,62(42),17530-17536.
MLA	Yang, Jiong,et al."Cyanide-Bridged Rope-like Chains Based on Trigonal-Bipyramidal [Fe₂Cu₃] Subunits".INORGANIC CHEMISTRY 62.42(2023):17530-17536.