南方科技大学知识苑(SUSTech KC): Recent Advances in Theoretical Studies on Cu-Mediated Bond Formation Mechanisms Involving Radicals

题名	Recent Advances in Theoretical Studies on Cu-Mediated Bond Formation Mechanisms Involving Radicals
作者	Liu，Ji Ren1,2 ; Xu，Guo Xiong 1; Liu，Li Gao 1; Zhang，Shuo Qing 1; Hong，Xin 1,3,4
发表日期	2024
DOI	10.1021/acscatal.3c06042
发表期刊	ACS Catalysis 影响因子和分区
EISSN	2155-5435
页码	2429-2454
摘要	Copper-catalyzed radical transformations establish a powerful toolkit to construct versatile complex organic compounds. The copper-mediated bond formation step of radicals plays a critical role in controlling chemo- and stereoselectivity of copper-catalyzed radical transformation reactions. This bond formation step involves three possible pathways: ion-type bond formation, radical substitution, and reductive elimination. This review highlights the recent advances in theoretical studies on mechanisms and controlling models on the selectivity of Cu-mediated radical-involved bond formation, providing a general mechanistic comprehension of this key elementary step in copper catalysis.
关键词	bond formation mechanism computational study copper catalysis mechanistic study radical transformation
相关链接	[Scopus记录]
收录类别	SCI ; EI
语种	英语
学校署名	其他
Scopus记录号	2-s2.0-85184829957
来源库	Scopus
引用统计	被引频次[WOS]：6
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/701615
专题	理学院_化学系深圳格拉布斯研究院
作者单位	1.Center of Chemistry for Frontier Technologies,Department of Chemistry,State Key Laboratory of Clean Energy Utilization,Zhejiang University,Hangzhou,310027,China 2.Shenzhen Grubbs Institute,Department of Chemistry,Southern University of Science and Technology,Shenzhen,518055,China 3.Beijing National Laboratory for Molecular Sciences,Beijing,Zhongguancun North First Street No. 2,100190,China 4.State Key Laboratory of Physical Chemistry of Solid Surfaces,Xiamen University,Xiamen,361005,China
第一作者单位	化学系; 深圳格拉布斯研究院
推荐引用方式 GB/T 7714	Liu，Ji Ren,Xu，Guo Xiong,Liu，Li Gao,et al. Recent Advances in Theoretical Studies on Cu-Mediated Bond Formation Mechanisms Involving Radicals[J]. ACS Catalysis,2024:2429-2454.
APA	Liu，Ji Ren,Xu，Guo Xiong,Liu，Li Gao,Zhang，Shuo Qing,&Hong，Xin.(2024).Recent Advances in Theoretical Studies on Cu-Mediated Bond Formation Mechanisms Involving Radicals.ACS Catalysis,2429-2454.
MLA	Liu，Ji Ren,et al."Recent Advances in Theoretical Studies on Cu-Mediated Bond Formation Mechanisms Involving Radicals".ACS Catalysis (2024):2429-2454.