南方科技大学知识苑(SUSTech KC): Palladium-Catalyzed Regioselective B(3,5)-Dialkenylation and B(4)-Alkenylation of o-Carboranes

题名	Palladium-Catalyzed Regioselective B(3,5)-Dialkenylation and B(4)-Alkenylation of o-Carboranes
作者	Yuan, Shasha 1,2; Zhang, Huifang 2; Qiu, Zaozao 2,3; Xie, Zuowei2,4,5
通讯作者	Qiu, Zaozao; Xie, Zuowei
发表日期	2023
DOI	10.1021/acs.joc.3c02496
发表期刊	Journal of Organic Chemistry 影响因子和分区
ISSN	0022-3263
EISSN	1520-6904
卷号	89 期号:4
摘要	Picolyl group directed B(3,5)-dialkenylation and B(4)-monoalkenylation of o-carboranes has been developed with a very low palladium catalyst loading. The degree of substitution is determined by the cage C(2)-substituents due to steric reasons. On the basis of experimental results, a plausible mechanism is proposed including electrophilic palladation and alkyne insertion followed by protonation. © 2024 American Chemical Society
相关链接	[来源记录]
收录类别	EI ; SCI
语种	英语
学校署名	通讯
资助项目	This work was supported by the grants from the National Natural Science Foundation of China (Project No. 92056106 to Z.Q.), the Research Grants Council of HKSAR (Project No. 14305420 to Z.X.), and the Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, CAS.
WOS研究方向	Chemistry
WOS类目	Chemistry, Organic
WOS记录号	WOS:001160868600001
出版者	American Chemical Society
EI入藏号	20240715541423
EI主题词	Palladium
EI分类号	Precious Metals:547.1 ; Chemical Agents and Basic Industrial Chemicals:803 ; Chemical Products Generally:804
ESI学科分类	CHEMISTRY
来源库	EV Compendex
引用统计	被引频次[WOS]：1
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/706400
专题	理学院_化学系深圳格拉布斯研究院
作者单位	1.School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai; 200093, China 2.Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, Shanghai; 200032, China 3.Innovation Institute of Carbon Neutrality and International Joint Laboratory of Catalytic Chemistry, Department of Chemistry, College of Sciences, Shanghai University, Shanghai; 200444, China 4.Department of Chemistry, The Chinese University of Hong Kong, Shatin, N. T., Hong Kong, Hong Kong 5.Shenzhen Grubbs Institute and Department of Chemistry, Southern University of Science and Technology, Shenzhen; 518055, China
通讯作者单位	化学系; 深圳格拉布斯研究院
推荐引用方式 GB/T 7714	Yuan, Shasha,Zhang, Huifang,Qiu, Zaozao,et al. Palladium-Catalyzed Regioselective B(3,5)-Dialkenylation and B(4)-Alkenylation of o-Carboranes[J]. Journal of Organic Chemistry,2023,89(4).
APA	Yuan, Shasha,Zhang, Huifang,Qiu, Zaozao,&Xie, Zuowei.(2023).Palladium-Catalyzed Regioselective B(3,5)-Dialkenylation and B(4)-Alkenylation of o-Carboranes.Journal of Organic Chemistry,89(4).
MLA	Yuan, Shasha,et al."Palladium-Catalyzed Regioselective B(3,5)-Dialkenylation and B(4)-Alkenylation of o-Carboranes".Journal of Organic Chemistry 89.4(2023).