| 题名 | Chiral phosphoric acid catalyzed redox deracemization of triarylmethanes |
| 作者 | |
| 通讯作者 | Li，Pengfei; Sun，Jianwei |
| 发表日期 | 2023
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| DOI | |
| 发表期刊 | |
| EISSN | 2769-5247
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| 卷号 | 3期号:3 |
| 摘要 | Described here is the first deracemization of triaryl-substituted carbon stereocenters, which is in contrast to the well-established processes to deracemize monoaryl-and diaryl-substituted ones. This one-pot redox process involves in situ generation of a para-quinone methide intermediate followed by asymmetric reduction by chiral phosphoric acid catalysis. A wide range of highly enantioenriched triarylmethanes could be generated with high efficiency under mild conditions. |
| 关键词 | |
| 相关链接 | [Scopus记录] |
| 收录类别 | |
| 语种 | 英语
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| 学校署名 | 通讯
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| 引用统计 | |
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/719148 |
| 专题 | 理学院_化学系 理学院 深圳格拉布斯研究院 |
| 作者单位 | 1.Department of Chemistry and the Hong Kong Branch of Chinese National Engineering Research Centre for Tissue Restoration & Reconstruction,The Hong Kong University of Science and Technology,999077,Hong Kong 2.Shenzhen Grubbs Institute and Department of Chemistry,Guangdong Provincial Key Laboratory of Catalysis,College of Science,Southern University of Science and Technology,Shenzhen,Guangdong,518055,China 3.Shenzhen Bay Laboratory,Shenzhen,Guangdong,518107,China 4.Shenzhen Research Institute,The Hong Kong University of Science and Technology,Shenzhen,Guangdong,518057,China |
| 第一作者单位 | 化学系; 深圳格拉布斯研究院; 理学院 |
| 通讯作者单位 | 化学系; 深圳格拉布斯研究院; 理学院 |
| 推荐引用方式 GB/T 7714 |
Liu，Chang,Li，Zhiyang,Li，Pengfei,et al. Chiral phosphoric acid catalyzed redox deracemization of triarylmethanes[J]. Chemical Synthesis,2023,3(3).
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| APA |
Liu，Chang,Li，Zhiyang,Li，Pengfei,&Sun，Jianwei.(2023).Chiral phosphoric acid catalyzed redox deracemization of triarylmethanes.Chemical Synthesis,3(3).
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| MLA |
Liu，Chang,et al."Chiral phosphoric acid catalyzed redox deracemization of triarylmethanes".Chemical Synthesis 3.3(2023).
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| 条目包含的文件 | 条目无相关文件。 | |||||
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