Metal-organic frameworks for carbon-neutral catalysis: State of the art, challenges, and opportunities

Liu，Mingxu1; Peng，Yong2; Chen，Weibin3; Cao，Shuang4; Chen，Shougang1; Lu Meng，Fan1; Jin，Yongcheng1; Hou，Chun Chao1; Zou，Ruqiang3; Xu，Qiang5

2024-05-01

10.1016/j.ccr.2024.215726

Coordination Chemistry Reviews   影响因子和分区

0010-8545

To address environmental problems and growing energy demands, reducing CO emissions and developing sustainable clean energy are becoming increasingly crucial. In this context, carbon dioxide reduction reaction (CORR) and hydrogen evolution reaction (HER) are gaining significant attention as promising technologies for energy conversion utilizing renewable energy sources. However, developing advanced and highly efficient catalysts is essential to make these applications feasible. Metal-organic frameworks (MOFs), a new class of porous crystalline materials, have shown great potential in designing such catalysts for CORR and HER. Their ordered and tailorable structures, ultrahigh surface areas, and well-defined active sites make them ideal for this purpose. This review discusses the current advances, remaining challenges and future opportunities of MOF-based catalysts in CORR and HER. First, the strategies for synthesizing and modifying MOF-based catalysts are overviewed, including pristine MOFs, MOF composites and MOF derivatives. Then, the advanced characterization techniques are showcased to provide reaction mechanism insights. Moreover, the recent advances of MOF-based catalysts in both CORR and HER are compiled in detail, highlighting the structure–activity relationship of MOF materials. Finally, the challenges and outlooks of MOF-based catalysts for CORR and HER are described. This review provides a systemic and in-depth insight into MOF-based catalyst for CORR and HER, hoping that this timely and comprehensive review can shed light on the upcoming research horizons of these prosperous areas.

Carbon dioxide reduction reaction Carbon-neutral catalysis Hydrogen evolution reaction Metal-organic frameworks

SCI

英语

其他

CHEMISTRY

2-s2.0-85186392931

Scopus

1.School of Materials Science and Engineering,Ocean University of China,Qingdao,Shandong,266100,China
2.Leibniz Institute for Catalysis e. V.,Rostock,Albert-Einstein-Strasse 29a,18059,Germany
3.School of Materials Science and Engineering,Peking University,Beijing,100871,China
4.College of Chemistry and Chemical Engineering,Institute for Sustainable Energy and Resources,Qingdao University,Qingdao,Shandong,266071,China
5.Shenzhen Key Laboratory of Micro/Nano-Porous Functional Materials (SKLPM),SUSTech-Kyoto University Advanced Energy Materials Joint Innovation Laboratory (SKAEM-JIL),Key University,Laboratory of Highly Efficient Utilization of Solar Energy and Sustainable Development of Guangdong,Department of Chemistry and Department of Materials Science and Engineering,Southern University of Science and Technology (SUSTech),Shenzhen,518055,China

Liu，Mingxu,Peng，Yong,Chen，Weibin,et al. Metal-organic frameworks for carbon-neutral catalysis: State of the art, challenges, and opportunities[J]. Coordination Chemistry Reviews,2024,506.

Liu，Mingxu.,Peng，Yong.,Chen，Weibin.,Cao，Shuang.,Chen，Shougang.,...&Xu，Qiang.(2024).Metal-organic frameworks for carbon-neutral catalysis: State of the art, challenges, and opportunities.Coordination Chemistry Reviews,506.

Liu，Mingxu,et al."Metal-organic frameworks for carbon-neutral catalysis: State of the art, challenges, and opportunities".Coordination Chemistry Reviews 506(2024).