南方科技大学知识苑(SUSTech KC): MXene层间结构调控对其光响应与电磁屏蔽性能影响的研究

题名	MXene层间结构调控对其光响应与电磁屏蔽性能影响的研究
其他题名	RESEARCH ON THE INFLUENCE OF MXENE INTERLAYER STRUCTURE CONTROL ON ITS OPTICAL RESPONSE AND ELECTROMAGNETIC SHIELDING PERFORMANCE
姓名	王培智
姓名拼音	WANG Peizhi
学号	12132078
学位类型	硕士
学位专业	070207 光学
学科门类/专业学位类别	07 理学
导师	徐保民
导师单位	材料科学与工程系
论文答辩日期	2024-05-09
论文提交日期	2024-06-24
学位授予单位	南方科技大学
学位授予地点	深圳
摘要	二维过渡金属碳氮化物（MXene）具有可调控的层间结构和高的导电性，使其在光探测和电磁屏蔽领域受到高度关注。然而，对于MXene在针对红外光响应和X波段电磁屏蔽性能方面的层间结构调控的研究还相对缺乏。其中的主要原因是因为缺少对MXene层间结构的精细控制，这不仅导致了其红外响应性能的批次间差异，还影响了其在X波段的吸波性能。鉴于此，本研究围绕MXene材料层间结构的精细调控开展深入研究，成功制备了光探测器和电磁屏蔽薄膜，并从调控MXene层间结构的角度出发，阐释了其响应机理并优化了吸波性能。 MXene的层间化学可调节性在多种探测器应用中展现出显著的应用前景。然而，其层间物质的变化导致光响应性能的不一致，主要归因于其复杂的电阻特性。为此，本研究通过分别构建单层与多层MXene结构，深入分析了其光响应行为。实验结果表明，在光照作用下，单层MXene的电阻值能够增加到100.10%，并能在1秒内迅速恢复，这主要是由材料的本征电阻变化引起的。相比之下，多层MXene在光照下电阻值快速降至99.60%，恢复过程则需要约15秒，这主要是多层结构中的插层效应主导的电阻变化。实验还发现会出现一种过渡态情况，其中MXene的电阻先是增加然后迅速减少，这一现象可归因于两种状态下弛豫时间的差异。此项研究不仅阐释了MXene层状结构对光响应的影响，还总结了不同层状结构下的主要响应机制，从而为实现MXene光探测器的响应一致性提供理论基础。在X波段频率下，MXene因其卓越的导电性和独特的层间结构而在电磁屏蔽领域受到重视。然而，层间水分的存在影响其电导率以及层内空间结构，进而限制其吸波性能。本论文通过激光处理技术去除层间水分，使MXene的导电性和结构疏松度得到显著提升，电磁屏蔽性能增强了5 dB。更重要的是，激光处理前后MXene的表面性质从亲水转变为疏水，使得MXene能够与液态金属镓进行有效复合。复合后的材料在30 μm的厚度下，屏蔽性能超过90 dB。这种激光处理方法为MXene与其他金属材料的复合开辟了新的途径，也为未来高效电磁屏蔽材料的设计提供了新的思路。
其他摘要	Two-dimensional transition metal carbonitrides (MXenes) have tunable interlayer structures and high electrical conductivity, which have attracted great attention in the fields of light detection and electromagnetic shielding. Nonetheless, research on the modulation of MXene's interlayer structure for infrared response and X-band electromagnetic shielding performance remains relatively sparse. This gap primarily stems from a lack of precise control over MXene's interlayer structure, affecting not only batch-to-batch consistency in infrared response but also its absorption capabilities in the X-band. Addressing this, our study embarked on an in-depth exploration of MXene materials, successfully fabricating detectors and electromagnetic shielding films. By focusing on the adjustment of the MXene interlayer structure, we elucidated its response mechanism and enhanced its absorption performance. The tunability of MXene's interlayer chemistry presents significant prospects for various detector applications. However, variations in the interlayer content have led to inconsistencies in light response performance, largely due to its complex resistive properties. To tackle this issue, our research constructed single and multi-layer MXene structures to thoroughly analyze their light-responsive behaviors. Experimental outcomes indicated that under illumination, the resistance of single-layer MXene could increase by 100.10% and rapidly recover within one second, primarily driven by intrinsic resistance changes. In contrast, multi-layer MXene exhibited a swift decrease in resistance to 99.60% under light, with a recovery period of about 15 seconds, where the interlayer effect predominantly influenced the resistance change. Notably, an intermediate state was observed, in which MXene's resistance first increased and then quickly decreased, attributable to the differential relaxation times between the two states. This study not only clarified the impact of MXene's layered structure on its light responsiveness but also summarized the main response mechanisms across different layer structures, thereby laying a theoretical foundation for achieving consistent responses in MXene detectors. In the X-band frequency range, MXene's exceptional conductivity and unique interlayer structure have made it a subject of interest in the electromagnetic shielding domain. However, the presence of interlayer water impacted its conductivity and interlayer spatial structure, subsequently limiting its absorption performance. By employing laser treatment technology to remove interlayer water, the conductivity and structural looseness of MXene were significantly enhanced, improving the electromagnetic shielding effectiveness by 5 dB. More crucially, laser treatment altered MXene's surface properties from hydrophilic to hydrophobic, facilitating effective compounding with liquid metal gallium. The composite material exhibited shielding effectiveness up to 90 dB at a thickness of 30 μm. This laser treatment approach has opened new avenues for combining MXene with other metal materials, also offering fresh insights for the design of future efficient electromagnetic interference shielding materials.
关键词	二维材料 MXene 层间结构红外探测电磁屏蔽
语种	中文
培养类别	独立培养
入学年份	2021
学位授予年份	2024-07
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所在学位评定分委会	材料科学与工程
国内图书分类号	TB332
来源库	人工提交
成果类型	学位论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/766019
专题	南方科技大学工学院_材料科学与工程系
推荐引用方式 GB/T 7714	王培智. MXene层间结构调控对其光响应与电磁屏蔽性能影响的研究[D]. 深圳. 南方科技大学,2024.

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