Investigation and analysis of the macro- and micro-responses of bentonite-sand mixtures to temperature

Li, An1; Feng, Wei-Qiang2; Chen, Ze-Jian1; Mailk, Numan1; Yin, Jian-Hua1; Zhou, Chao1

2024-06-01

10.1016/j.gete.2024.100565

GEOMECHANICS FOR ENERGY AND THE ENVIRONMENT   影响因子和分区

2352-3808

Bentonite-sand mixture has been proposed as a buffer material of high-level radioactive waste (HLW) repositories in many countries. The elevated temperature in HLW repositories significantly influences the properties and behaviour of the surrounding buffers. However, to date the mechanism of temperature effects on the behaviour of the bentonite buffer is not well understood. This study is aimed at clarifying the macro- and micro-responses of bentonite-sand mixtures by conducting cone penetration test, rheometer test, flask volumetric test, scanning electron microscopy (SEM) and mercury intrusion porosimetry (MIP) at different temperatures. The results from macro-experiments show that the liquid limit and yield stress increased while bound water content decreased with increasing temperature. The normalized relationships disclose the sand content dramatically affects the degree of temperature influence on the macro-behaviour. SEM and MIP results present that the contact manner between particles converted from edge-to-face to the edge-to-edge association and some intra-aggregate pores merged to form inter-aggregate pores as temperature increases. The mechanisms of the increasing temperature influence on the responses of bentonite-sand mixtures can be inferred that: 1) the diffuse double layer is supposed to decrease since more ions were electrolyzed from montmorillonite particles, thereby, increasing the ion concentration and changing the ion valence; 2) the slight shrinkage of diffuse double layer produced nano-fissures, causing water-hold capacity to increase; 3) the temperature-induced transition from bound water into free water results in an increase of liquid volume; 4) increasing temperature led to increased inter-particle repulsive force. Furthermore, an empirical model was proposed to predict the yield stress of bentonite dispersion incorporating the combined effects of sand content and temperature.

Temperature Bound water Liquid limit Bentonite Micro -response Diffuse double layer

SCI ; EI

英语

通讯

National Natural Science Foundation of China[52278356] ; Natural Science Foundation of Guangdong Province, China[2022A1515010118] ; Shenzhen Science and Technology Innovation Commission["JCYJ20230807093305011","JCYJ20210324105210028"]

Energy & Fuels ; Engineering ; Geology

Energy & Fuels ; Engineering, Geological ; Geosciences, Multidisciplinary

WOS:001248456400001

ELSEVIER

Web of Science

1.Hong Kong Polytech Univ, Dept Civil & Environm Engn, Hong Kong, Peoples R China
2.Southern Univ Sci & Technol, Dept Ocean Sci & Engn, Shenzhen, Peoples R China

Li, An,Feng, Wei-Qiang,Chen, Ze-Jian,et al. Investigation and analysis of the macro- and micro-responses of bentonite-sand mixtures to temperature[J]. GEOMECHANICS FOR ENERGY AND THE ENVIRONMENT,2024,38.

Li, An,Feng, Wei-Qiang,Chen, Ze-Jian,Mailk, Numan,Yin, Jian-Hua,&Zhou, Chao.(2024).Investigation and analysis of the macro- and micro-responses of bentonite-sand mixtures to temperature.GEOMECHANICS FOR ENERGY AND THE ENVIRONMENT,38.

Li, An,et al."Investigation and analysis of the macro- and micro-responses of bentonite-sand mixtures to temperature".GEOMECHANICS FOR ENERGY AND THE ENVIRONMENT 38(2024).