南方科技大学知识苑(SUSTech KC): Electrocatalytic, Sm-Promoted Synthesis of Aminoarenes from Nitroaromatic Derivatives in MeOH

题名	Electrocatalytic, Sm-Promoted Synthesis of Aminoarenes from Nitroaromatic Derivatives in MeOH
作者	Zhang, Yu-Feng1,2,3 ; Schulz, Emmanuelle 1; Mellah, Mohamed 1
通讯作者	Mellah, Mohamed
发表日期	2024-06-01
DOI	10.1002/cctc.202400303
发表期刊	CHEMCATCHEM 影响因子和分区
ISSN	1867-3880
EISSN	1867-3899
摘要	["A new mild and chemoselective method for the preparation of various aminoarenes is described, based on the electrochemical catalytic reduction of nitroaryl derivatives promoted by samarium salts in methanol. The reactions are carried out in air, in an undivided electrochemical cell, at room temperature and tolerate a wide range of functional groups, including some reducible ones, without leading to by-products. This procedure is also effective for the complete reduction of challenging substrates, namely those capable of coordinating metals, traditionally leading to the need for drastic conditions in terms of pressure, reaction time or temperature. 47 examples are described, including one nitroalkane, and all lead to the targeted reduced product in yields that are almost always over 90 %.","The preparation of various aminoarenes is described based on the Sm-promoted catalytic electrochemical reduction of corresponding nitroarenes. This mild procedure tolerates a wide range of functional groups and yields the targeted products in almost all cases in excess of 90 %. image"]
关键词	aminoarenes electrocatalysis nitroarenes reduction samarium
相关链接	[来源记录]
收录类别	SCI ; EI
语种	英语
学校署名	其他
WOS研究方向	Chemistry
WOS类目	Chemistry, Physical
WOS记录号	WOS:001241580300001
出版者	WILEY-V C H VERLAG GMBH
来源库	Web of Science
引用统计
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/788058
专题	深圳格拉布斯研究院理学院_化学系
作者单位	1.Univ Paris Saclay, Inst Chim Mol & Mat Orsay, CNRS, F-91190 Orsay, France 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Peoples R China 3.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China
第一作者单位	深圳格拉布斯研究院; 化学系
推荐引用方式 GB/T 7714	Zhang, Yu-Feng,Schulz, Emmanuelle,Mellah, Mohamed. Electrocatalytic, Sm-Promoted Synthesis of Aminoarenes from Nitroaromatic Derivatives in MeOH[J]. CHEMCATCHEM,2024.
APA	Zhang, Yu-Feng,Schulz, Emmanuelle,&Mellah, Mohamed.(2024).Electrocatalytic, Sm-Promoted Synthesis of Aminoarenes from Nitroaromatic Derivatives in MeOH.CHEMCATCHEM.
MLA	Zhang, Yu-Feng,et al."Electrocatalytic, Sm-Promoted Synthesis of Aminoarenes from Nitroaromatic Derivatives in MeOH".CHEMCATCHEM (2024).