Boron-Stereogenic Compounds: Synthetic Developments and Opportunities

Guo, Yonghong1; Zu, Bing2,3; Du Chen, Cadmus2,3; He, Chuan2,3

2024-05-01

10.1002/cjoc.202400130

CHINESE JOURNAL OF CHEMISTRY   影响因子和分区

1001-604X

1614-7065

["The 21st century has witnessed a continuous evolution in the development of boron-stereogenic chemistry. Since the 1990s, various innovations for the synthesis of tetracoordinate boron-stereogenic compounds, which exhibited great potential applications, have been demonstrated by synthetic chemists. This paper reviews the significant progress and recent advances towards the assembly of enantioenriched boron-stereogenic compounds, and hopes to shed light on new perspectives and inspire further research in this emerging field.","Tetracoordinate organoborons are a highly important class of molecules, that have found wide applications in areas ranging from synthetic chemistry, medicinal chemistry, to materials science. In this review, we summarized and discussed the significant progress and recent advances in the synthesis and application of enantioenriched tetracoordinate boron-stereogenic compounds, according to the synthetic method: (1) resolution of racemates, (2) chiral substrate induced asymmetric synthesis, and (3) asymmetric catalysis. image"]

Chiral organoboron Boron-stereogenic compounds Chiral resolution Asymmetric synthesis Asymmetric catalysis Chirality Heterocycles Chelates

SCI

英语

通讯

National Natural Science Foundation of China["22122102","22271134"] ; Guangdong Provincial Key Laboratory of Catalysis[2020B121201002] ; Guangdong Pearl River Talent Program[2019QN01Y628] ; Hebei Province Innovation Capability Enhancement Plan Project[22567632H] ; null[RCJC20221008092723013] ; null[JCYJ20230807093104009]

Chemistry

Chemistry, Multidisciplinary

WOS:001231703800001

WILEY-V C H VERLAG GMBH

CHEMISTRY

Web of Science

1.Hebei Univ, Coll Chem & Mat Sci, Key Lab Med Chem & Mol Diag, Key Lab Chem Biol Hebei Prov,Minist Educ, Baoding 071002, Hebei, Peoples R China
2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Guangdong, Peoples R China
3.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen 518055, Guangdong, Peoples R China

Guo, Yonghong,Zu, Bing,Du Chen, Cadmus,et al. Boron-Stereogenic Compounds: Synthetic Developments and Opportunities[J]. CHINESE JOURNAL OF CHEMISTRY,2024.

Guo, Yonghong,Zu, Bing,Du Chen, Cadmus,&He, Chuan.(2024).Boron-Stereogenic Compounds: Synthetic Developments and Opportunities.CHINESE JOURNAL OF CHEMISTRY.

Guo, Yonghong,et al."Boron-Stereogenic Compounds: Synthetic Developments and Opportunities".CHINESE JOURNAL OF CHEMISTRY (2024).