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题名

Photodissociation dynamics of SO2 via the G1B1 state: The O(1D2) and O(1S0) product channels

作者
通讯作者Chang, Yao; Yu, Shengrui; Yuan, Kaijun
发表日期
2024-04-28
DOI
发表期刊
ISSN
0021-9606
EISSN
1089-7690
卷号160期号:16
摘要
Produced by both nature and human activities, sulfur dioxide (SO2) is an important species in the earth's atmosphere. SO2 has also been found in the atmospheres of other planets and satellites in the solar system. The photoabsorption cross sections and photodissociation of SO2 have been studied for several decades. In this paper, we reported the experimental results for photodissociation dynamics of SO2 via the G1B1 state. By analyzing the images from the time-sliced velocity map ion imaging method, the vibrational state population distributions and anisotropy parameters were obtained for the O(1D2) + SO(X3 Sigma-, a1 Delta, b1 Sigma+) and O(1S0) + SO(X3 Sigma-) channels, and the branching ratios for the channels O(1D2) + SO(X3 Sigma-), O(1D2) + SO(a1 Delta), and O(1D2) + SO(b1 Sigma+) were determined to be similar to 0.3, similar to 0.6, and similar to 0.1, respectively. The SO products were dominant in electronically and rovibrationally excited states, which may have yet unrecognized roles in the upper planetary atmosphere.
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收录类别
SCI ; EI
语种
英语
学校署名
其他
资助项目
the National Natural Science Foundation of China[22288201] ; National Natural Science Foundation of China[GJJSTD20220001] ; Scientific Instrument Developing Project of the Chinese Academy of Sciences[2021ZD0303304] ; Innovation Program for Quantum Science and Technology["2019ZT08L455","2019JC01X091"] ; Guangdong Science and Technology Program[ZDSYS20200421111001787]
WOS研究方向
Chemistry ; Physics
WOS类目
Chemistry, Physical ; Physics, Atomic, Molecular & Chemical
WOS记录号
WOS:001208022000011
出版者
ESI学科分类
CHEMISTRY
来源库
Web of Science
引用统计
成果类型期刊论文
条目标识符http://sustech.caswiz.com/handle/2SGJ60CL/788569
专题理学院_化学系
南方科技大学
作者单位
1.Chinese Acad Sci, State Key Lab Mol React Dynam, Dalian Coherent Light Source & Dalian Inst Chem Ph, 457 Zhongshan Rd, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Zhejiang Normal Univ, Hangzhou Inst Adv Studies, 1108 Gengwen Rd, Hangzhou 311231, Zhejiang, Peoples R China
4.Hefei Natl Lab, Hefei 230088, Peoples R China
5.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China
6.Southern Univ Sci & Technol, Coll Sci, Ctr Adv Light Source Res, Shenzhen 518055, Peoples R China
推荐引用方式
GB/T 7714
Wu, Yucheng,Sun, Jitao,Li, Zhenxing,et al. Photodissociation dynamics of SO2 via the G1B1 state: The O(1D2) and O(1S0) product channels[J]. JOURNAL OF CHEMICAL PHYSICS,2024,160(16).
APA
Wu, Yucheng.,Sun, Jitao.,Li, Zhenxing.,Zhang, Zhaoxue.,Luo, Zijie.,...&Yang, Xueming.(2024).Photodissociation dynamics of SO2 via the G1B1 state: The O(1D2) and O(1S0) product channels.JOURNAL OF CHEMICAL PHYSICS,160(16).
MLA
Wu, Yucheng,et al."Photodissociation dynamics of SO2 via the G1B1 state: The O(1D2) and O(1S0) product channels".JOURNAL OF CHEMICAL PHYSICS 160.16(2024).
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