Hierarchically Ordered Pore Engineering of Metal-Organic Framework-Based Materials for Electrocatalysis

Li, Xiaofang1; Wu, Xin-Tao1,2,3; Xu, Qiang4,5; Zhu, Qi-Long1,2,3,6

2024-07-01

10.1002/adma.202401926

ADVANCED MATERIALS   影响因子和分区

0935-9648

1521-4095

["Ordered pore engineering that embeds uniform pores with periodic alignment in electrocatalysts opens up a new avenue for achieving further performance promotion. Hierarchically ordered porous metal-organic frameworks (HOP-MOFs) possessing multilevel pores with ordered distribution are the promising precursors for the exploration of ordered porous electrocatalysts, while the scalable acquisition of HOP-MOFs with editable components and adjustable pore size regimes is critical. This review presents recent progress on hierarchically ordered pore engineering of MOF-based materials for enhanced electrocatalysis. The synthetic strategies of HOP-MOFs with different pore size regimes, including the self-assembly guided by reticular chemistry, surfactant, nanoemulsion, and nanocasting, are first introduced. Then the applications of HOP-MOFs as the precursors for exploring hierarchically ordered porous electrocatalysts are summarized, selecting representatives to highlight the boosted performance. Especially, the intensification of molecule and ion transport integrated with optimized electron transfer and site exposure over the hierarchically ordered porous derivatives are emphasized to clarify the directional transfer and integration effect endowed by ordered pore engineering. Finally, the remaining scientific challenges and an outlook of this field are proposed. It is hoped that this review will guide the hierarchically ordered pore engineering of nanocatalysts for boosting the catalytic performance and promoting the practical applications.","Progress on hierarchically ordered pore engineering of metal-organic frameworks-based materials for enhanced electrocatalysis is reviewed. Especially, the intensification of molecule and ion transport integrated with the optimized electron transfer and site exposure over the hierarchically ordered porous derivatives during the electrocatalytic applications is emphasized to clarify the directional transfer and integration effect endowed by ordered pore engineering. image"]

electrocatalysis hierarchically ordered pore engineering mass transfer metal-organic frameworks structure-activity relationship

SCI ; EI

英语

其他

National Natural Science Foundation of China (NSFC)["22175174","22205235","52332007"] ; Natural Science Foundation of Fujian Province["2021J06033","2022L3092"] ; null[2021YFA1500402]

Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics

Chemistry, Multidisciplinary ; Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary ; Physics, Applied ; Physics, Condensed Matter

WOS:001209022000001

WILEY-V C H VERLAG GMBH

20241816013985

Electrocatalysis ; Electrocatalysts ; Electrolysis ; Nanocatalysts ; Pore size ; Professional aspects

Mass Transfer:641.3 ; Nanotechnology:761 ; Electrochemistry:801.4.1 ; Chemical Reactions:802.2 ; Chemical Agents and Basic Industrial Chemicals:803 ; Engineering Professional Aspects:901.1 ; Physical Properties of Gases, Liquids and Solids:931.2 ; Materials Science:951

MATERIALS SCIENCE

Web of Science

1.Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
2.Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Southern Univ Sci & Technol SUSTech, Dept Chem, Shenzhen Key Lab Micro Nanoporous Funct Mat SKLPM, Shenzhen 518055, Peoples R China
5.Southern Univ Sci & Technol SUSTech, Dept Mat Sci & Engn, Shenzhen 518055, Peoples R China
6.Zhejiang Sci Tech Univ, Sch Mat Sci & Engn, Hangzhou 310018, Peoples R China

Li, Xiaofang,Wu, Xin-Tao,Xu, Qiang,et al. Hierarchically Ordered Pore Engineering of Metal-Organic Framework-Based Materials for Electrocatalysis[J]. ADVANCED MATERIALS,2024,36(27).

Li, Xiaofang,Wu, Xin-Tao,Xu, Qiang,&Zhu, Qi-Long.(2024).Hierarchically Ordered Pore Engineering of Metal-Organic Framework-Based Materials for Electrocatalysis.ADVANCED MATERIALS,36(27).

Li, Xiaofang,et al."Hierarchically Ordered Pore Engineering of Metal-Organic Framework-Based Materials for Electrocatalysis".ADVANCED MATERIALS 36.27(2024).