| 题名 | X-type silyl ligands for transition-metal catalysis |
| 作者 | |
| 通讯作者 | Ge, Yicong; He, Chuan |
| 发表日期 | 2024-05-07
|
| DOI | |
| 发表期刊 | |
| ISSN | 0306-0012
|
| EISSN | 1460-4744
|
| 卷号 | 53期号:9 |
| 摘要 | ["Given the critical importance of novel ligand development for transition-metal (TM) catalysis, as well as the resurgence of the field of organosilicon chemistry and silyl ligands, to summarize the topic of X-type silyl ligands for TM catalysis is highly attractive and timely. This review particularly emphasizes the unique sigma-donating characteristics and trans-effects of silyl ligands, highlighting their crucial roles in enhancing the reactivity and selectivity of various catalytic reactions, including small molecule activation, Kumada cross-coupling, hydrofunctionalization, C-H functionalization, and dehydrogenative Si-O coupling reactions. Additionally, future developments in this field are also provided, which would inspire new insights and applications in catalytic synthetic chemistry.","This review summarizes the developments of X-type silyl ligands for transition-metal catalysis, elucidating the unique features of sigma-donating ability and trans-influence of silyl-metal catalysts."] |
| 相关链接 | [来源记录] |
| 收录类别 | |
| 语种 | 英语
|
| 学校署名 | 通讯
|
| 资助项目 | Science, Technology and Innovation Commission of Shenzhen Municipality["22122102","22271134"]
; National Natural Science Foundation of China[2020B121201002]
; Guangdong Provincial Key Laboratory of Catalysis[2019QN01Y628]
; Guangdong Pearl River Talent Program["RCJC20221008092723013","JCYJ20230807093104009"]
|
| WOS研究方向 | Chemistry
|
| WOS类目 | Chemistry, Multidisciplinary
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| WOS记录号 | WOS:001190273600001
|
| 出版者 | |
| ESI学科分类 | CHEMISTRY
|
| 来源库 | Web of Science
|
| 引用统计 |
被引频次[WOS]：6
|
| 成果类型 | 期刊论文 |
| 条目标识符 | http://sustech.caswiz.com/handle/2SGJ60CL/788800 |
| 专题 | 深圳格拉布斯研究院 理学院_化学系 |
| 作者单位 | 1.Harbin Inst Technol, Sch Chem & Chem Engn, Heilongjiang Prov, Harbin 150080, Heilongjiang, Peoples R China 2.Southern Univ Sci & Technol, Shenzhen Grubbs Inst, Shenzhen 518055, Guangdong, Peoples R China 3.Southern Univ Sci & Technol, Dept Chem, Guangdong Prov Key Lab Catalysis, Shenzhen, Guangdong, Peoples R China |
| 第一作者单位 | 深圳格拉布斯研究院; 化学系 |
| 通讯作者单位 | 深圳格拉布斯研究院; 化学系 |
| 推荐引用方式 GB/T 7714 |
Gao, Jihui,Ge, Yicong,He, Chuan. X-type silyl ligands for transition-metal catalysis[J]. CHEMICAL SOCIETY REVIEWS,2024,53(9).
|
| APA |
Gao, Jihui,Ge, Yicong,&He, Chuan.(2024).X-type silyl ligands for transition-metal catalysis.CHEMICAL SOCIETY REVIEWS,53(9).
|
| MLA |
Gao, Jihui,et al."X-type silyl ligands for transition-metal catalysis".CHEMICAL SOCIETY REVIEWS 53.9(2024).
|
| 条目包含的文件 | 条目无相关文件。 | |||||
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