南方科技大学知识苑(SUSTech KC): Synthesis, Structure, and Magnetic Properties of Cyanurates RE 5(C3N3O3)(OH)12 (RE = Gd-Lu): Cryogenic Magnetocaloric Candidate Gd5(C3N3O3)(OH)12

题名	Synthesis, Structure, and Magnetic Properties of Cyanurates RE ₅(C₃N₃O₃)(OH)₁₂ (RE = Gd-Lu): Cryogenic Magnetocaloric Candidate Gd₅(C₃N₃O₃)(OH)₁₂
作者	Wang, Tianyu 1,2; Guo, Ruixin3,5 ; Liu, Qingxiong 1,2; Wu, Qian 1; Meng, Xianghe 1; Zhou, Zhengyang 4; Guo, Shu3,5 ; Xia, Mingjun 1
通讯作者	Guo, Shu; Xia, Mingjun
发表日期	2024-07-10
DOI	10.1021/acs.inorgchem.4c01569
发表期刊	INORGANIC CHEMISTRY 影响因子和分区
ISSN	0020-1669
EISSN	1520-510X
卷号	63 期号:29页码:13171-13175
摘要	Rare-earth (RE)-based frustrated magnets are fertile playgrounds for discovering exotic quantum phenomena and exploring adiabatic demagnetization refrigeration applications. Here, we report the synthesis, structure, and magnetic properties of a family of rare-earth cyanurates RE5(C3N3O3)(OH)(12) (RE = Gd-Lu) with an acentric space group P62m. Magnetic susceptibility chi(T) and isothermal magnetization M(H) measurements manifest that RE5(C3N3O3)(OH)(12) (RE = Gd, Dy-Yb) compounds exhibit no magnetic ordering down to 2 K, while Tb-5(C3N3O3)(OH)(12) shows long-range magnetic ordering around 3.6 K. Among them, magnetically frustrated spin-(7)/(2) Gd-5(C3N3O3)(OH)(12) shows long-range magnetic ordering around 1.25 K and a large magnetocaloric effect with a maximum magnetic entropy change Delta S-m of up to 58.1 J kg(-1) K-1 at Delta H = 7 T at liquid-helium temperature regimes.
相关链接	[来源记录]
收录类别	SCI ; EI
语种	英语
学校署名	通讯
资助项目	National Natural Science Foundation of China["52172011","22205091"] ; CAS Project for Young Scientists in Basic Research[YSBR-024]
WOS研究方向	Chemistry
WOS类目	Chemistry, Inorganic & Nuclear
WOS记录号	WOS:001274488100001
出版者	AMER CHEMICAL SOC
EI入藏号	20242916716358
EI主题词	Binary alloys ; Dysprosium alloys ; Holmium compounds ; Magnetic susceptibility ; Magnetocaloric effects ; Superfluid helium ; Terbium compounds
EI分类号	Rare Earth Metals:547.2 ; Magnetism: Basic Concepts and Phenomena:701.2 ; Chemical Products Generally:804 ; Inorganic Compounds:804.2
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/790009
专题	量子科学与工程研究院
作者单位	1.Chinese Acad Sci, Tech Inst Phys & Chem, Beijing Ctr Crystal Res & Dev, Key Lab Funct Crystals & Laser Technol, Beijing 100190, Peoples R China 2.Univ Chinese Acad Sci, Sch Future Technol, Beijing 100049, Peoples R China 3.Southern Univ Sci & Technol, Shenzhen Inst Quantum Sci & Engn, Shenzhen 518055, Peoples R China 4.Chinese Acad Sci, Shanghai Inst Ceram, Shanghai 200050, Peoples R China 5.Int Quantum Acad, Shenzhen 518048, Peoples R China
通讯作者单位	量子科学与工程研究院
推荐引用方式 GB/T 7714	Wang, Tianyu,Guo, Ruixin,Liu, Qingxiong,et al. Synthesis, Structure, and Magnetic Properties of Cyanurates RE ₅(C₃N₃O₃)(OH)₁₂ (RE = Gd-Lu): Cryogenic Magnetocaloric Candidate Gd₅(C₃N₃O₃)(OH)₁₂[J]. INORGANIC CHEMISTRY,2024,63(29):13171-13175.
APA	Wang, Tianyu.,Guo, Ruixin.,Liu, Qingxiong.,Wu, Qian.,Meng, Xianghe.,...&Xia, Mingjun.(2024).Synthesis, Structure, and Magnetic Properties of Cyanurates RE ₅(C₃N₃O₃)(OH)₁₂ (RE = Gd-Lu): Cryogenic Magnetocaloric Candidate Gd₅(C₃N₃O₃)(OH)₁₂.INORGANIC CHEMISTRY,63(29),13171-13175.
MLA	Wang, Tianyu,et al."Synthesis, Structure, and Magnetic Properties of Cyanurates RE ₅(C₃N₃O₃)(OH)₁₂ (RE = Gd-Lu): Cryogenic Magnetocaloric Candidate Gd₅(C₃N₃O₃)(OH)₁₂".INORGANIC CHEMISTRY 63.29(2024):13171-13175.