南方科技大学知识苑(SUSTech KC): Metal-Organic Framework Supported Low-Nuclearity Cluster Catalysts for Highly Selective Carbon Dioxide Electroreduction to Ethanol

题名	Metal-Organic Framework Supported Low-Nuclearity Cluster Catalysts for Highly Selective Carbon Dioxide Electroreduction to Ethanol
作者	Shao, Bing1,2 ; Huang, Du 3; Huang, Rui-Kang 4; He, Xing-Lu 1; Luo, Yan 1; Xiang, Yi-Lei 5; Jiang, Lin-bin 5; Dong, Min 1; Li, Shixiong 6; Zhang, Zhong 7; Huang, Jin 1
通讯作者	Huang, Jin
发表日期	2024-07-01
DOI	10.1002/anie.202409270
发表期刊	ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 影响因子和分区
ISSN	1433-7851
EISSN	1521-3773
摘要	It is still a great challenge to achieve high selectivity of ethanol in CO2 electroreduction reactions (CO2RR) because of the similar reduction potentials and lower energy barrier of possible other C2+ products. Here, we report a MOF-based supported low-nuclearity cluster catalysts (LNCCs), synthesized by electrochemical reduction of three-dimensional (3D) microporous Cu-based MOF, that achieves a single-product Faradaic efficiency (FE) of 82.5 % at -1.0 V (versus the reversible hydrogen electrode) corresponding to the effective current density is 8.66 mA cm(-2). By investigating the relationship between the species of reduction products and the types of catalytic sites, it is confirmed that the multi-site synergism of Cu LNCCs can increase the C-C coupling effect, and thus achieve high FE of CO2-to-ethanol. In addition, density functional theory (DFT) calculation and operando attenuated total reflectance surface-enhanced infrared absorption spectroscopy further confirmed the reaction path and mechanism of CO2-to-EtOH.
关键词	metal-organic frameworks low-nuclearity cluster electrocatalysis carbon dioxide reduction C2+ products
相关链接	[来源记录]
收录类别	SCI ; EI
语种	英语
学校署名	其他
资助项目	National Natural Science Foundation of China[21901051] ; Guangxi Natural Science Foundation of China[2022GXNSFBA035474]
WOS研究方向	Chemistry
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:001280903700001
出版者	WILEY-V C H VERLAG GMBH
ESI学科分类	CHEMISTRY
来源库	Web of Science
引用统计	被引频次[WOS]：2
成果类型	期刊论文
条目标识符	http://sustech.caswiz.com/handle/2SGJ60CL/790109
专题	理学院_化学系
作者单位	1.Guangxi Med Univ, Pharmaceut Coll, Nanning 530021, Peoples R China 2.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China 3.Guangxi Minzu Univ, Coll Chem & Chem Engn, Nanning 530006, Peoples R China 4.Hokkaido Univ, Res Inst Elect Sci, Sapporo 0010021, Japan 5.Guangxi Univ, Sch Chem & Chem Engn, Nanning 530004, Peoples R China 6.Wuzhou Univ, Sch Mech & Resource Engn, Wuzhou 543003, Guangxi, Peoples R China 7.Guangxi Normal Univ, Sch Chem & Pharmaceut Sci, Guilin 541004, Peoples R China
第一作者单位	化学系
推荐引用方式 GB/T 7714	Shao, Bing,Huang, Du,Huang, Rui-Kang,et al. Metal-Organic Framework Supported Low-Nuclearity Cluster Catalysts for Highly Selective Carbon Dioxide Electroreduction to Ethanol[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2024.
APA	Shao, Bing.,Huang, Du.,Huang, Rui-Kang.,He, Xing-Lu.,Luo, Yan.,...&Huang, Jin.(2024).Metal-Organic Framework Supported Low-Nuclearity Cluster Catalysts for Highly Selective Carbon Dioxide Electroreduction to Ethanol.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION.
MLA	Shao, Bing,et al."Metal-Organic Framework Supported Low-Nuclearity Cluster Catalysts for Highly Selective Carbon Dioxide Electroreduction to Ethanol".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2024).