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题名

Strained heterojunction enables high-performance, fully textured perovskite/silicon tandem solar cells

作者
通讯作者Yu, Cao; Huang, Haitao; Yao, Kai
发表日期
2024
DOI
发表期刊
EISSN
2542-4351
摘要
Integrating metal-halide perovskites with the industrially textured Czochralski silicon for perovskite/silicon tandem cells shows great promise for low-cost manufacturing and ideal light trapping. However, the conformal growth of high-quality perovskite film on fully textured silicon remains challenging due to the lack of effective regulation of structural evolution and residual strains. Here, we report a strain regulation strategy by forming a 3D/3D perovskite heterojunction at the buried interface through a vacuum-deposition method applicable to pyramidal texture. By tailoring the composition of buried buffer 3D perovskite, a controllable compressive strain is applied to the upper photoactive 3D perovskite, alleviating its residual tensile stress. We demonstrate that this strained heterostructure promotes the preferred crystal growth, reduces interfacial defect-induced recombination, and facilitates charge extraction. As a result, the fully textured perovskite/silicon tandem cell achieves a certified steady-state efficiency of 31.5% and retains over 95% of its initial efficiency after 800 h of continuous operation.
© 2024 Elsevier Inc.
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资助项目
We thank C. Zhou at Shanghai JinZhu Technology Co. Ltd. for assistance with confocal PL mapping measurement. The authors gratefully acknowledge the financial support from the National Natural Science Foundation of China (grant 62274080 ) and the Natural Science Foundation of Jiangxi Province, China ( 20224ACB214003 ). K.Y. also thanks for the support from the Thousand Talents Plan of Jiangxi Province ( jxsq2019201109 ). This work was also supported by the National Key R&D Plan Project (grant no. 2022YFB4200305 ) and the Prospective Basic Research Projects of CNPC (grant no. 2022DJ5407 ).
出版者
EI入藏号
20242916719354
EI主题词
Efficiency ; Heterojunctions ; Metal halides ; Perovskite solar cells ; Strain ; Textures
EI分类号
Minerals:482.2 ; Solar Cells:702.3 ; Semiconductor Devices and Integrated Circuits:714.2 ; Chemical Products Generally:804 ; Production Engineering:913.1 ; Materials Science:951
来源库
EV Compendex
引用统计
成果类型期刊论文
条目标识符http://sustech.caswiz.com/handle/2SGJ60CL/794638
专题工学院_机械与能源工程系
南方科技大学
工学院_碳中和能源研究院
作者单位
1.Institute of Photovoltaics, School of Physics and Materials Science, Nanchang University, Nanchang; 330031, China
2.Suzhou Maxwell Technologies Co. Ltd., Suzhou; 215200, China
3.Department of Applied Physics, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong
4.State Key Laboratory of Oil and Gas Equipment, CNPC Tubular Goods Research Institute, Shaanxi, Xi'an; 710077, China
5.Henan Key Laboratory of Infrared Materials & Spectrum Measures and Applications, Henan Normal University, Xinxiang; 453007, China
6.Shenzhen Key Laboratory of Intelligent Robotics and Flexible Manufacturing Systems, Department of Mechanical and Energy Engineering, SUSTech Energy Institute for Carbon Neutrality, Southern University of Science and Technology, Shenzhen; 518055, China
7.Shenzhen Institutes of Advanced Technology, Chinese Academy of Sciences, Shenzhen; 518055, China
8.Department of Materials Science & Engineering, City University of Hong Kong, Kowloon, Hong Kong
9.School of Materials and Energy, Yunnan University, Kunming; 650091, China
10.Ministry of Industry and Information Technology Key Lab of Micro-Nano Optoelectronic Information System, Harbin Institute of Technology (Shenzhen), Shenzhen; 518055, China
11.State Key Laboratory of Photovoltaic Science and Technology, Shanghai Frontiers Science Research Base of Intelligent Optoelectronics and Perception, Institute of Optoelectronics, Fudan University, Shanghai; 200433, China
推荐引用方式
GB/T 7714
Liu, Zhiliang,Xiong, Zhijun,Yang, Shaofei,et al. Strained heterojunction enables high-performance, fully textured perovskite/silicon tandem solar cells[J]. Joule,2024.
APA
Liu, Zhiliang.,Xiong, Zhijun.,Yang, Shaofei.,Fan, Ke.,Jiang, Long.,...&Yao, Kai.(2024).Strained heterojunction enables high-performance, fully textured perovskite/silicon tandem solar cells.Joule.
MLA
Liu, Zhiliang,et al."Strained heterojunction enables high-performance, fully textured perovskite/silicon tandem solar cells".Joule (2024).
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